Cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds

doi:10.1016/j.tet.2017.04.002

CORC > 过程工程研究所 > 中国科学院过程工程研究所 > 多相复杂系统国家重点实验室

	Cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds
	Ren, Tian-Lu 1,2; Xu, Bao-Hua 1,2; Mahmood, Sajid 1,2; Sun, Ming-Xue 3; Zhang, Suo-Jiang 1,2
刊名	TETRAHEDRON
	2017-05-18
卷号	73 期号:20 页码:2943-2948
关键词	Cobalt Oxidative Esterification c(Sp(3))-h Bond Activation Carboxylic Acid Peroxide
ISSN号	0040-4020
DOI	10.1016/j.tet.2017.04.002
文献子类	Article
英文摘要	A protocol for the cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds with carboxylic acids was developed in this work. Mechanistic studies revealed that C(sp(3))-H bond activation in the hydrocarbon was the turnover-limiting step and the in-situ formed [Co(III)]Ot-Bu did not engage in hydrogen atom abstraction (HAA) of a C H bond. This protocol was successfully incorporated into a synthetic pathway to beta-damascenone that avoided the use of NBS. (C) 2017 Elsevier Ltd. All rights reserved.
WOS关键词	Metal-free Conditions ; Allylic Oxidation ; Butyl Hydroperoxide ; Aromatic-aldehydes ; Carboxylic-acids ; Beta-damascenone ; Benzylic Esters ; Cyclic Ethers ; Olefins ; Activation
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000401210200012
资助机构	National Key Projects for Fundamental Research and Development of China(2016YFB0601303) ; National Natural Science Foundation of China(21476240) ; Key Program of National Natural Science Foundation of China(91434203) ; Instrument Developing Project of the Chinese Academy of Sciences(YZ201521) ; CAS (Chinese Academy of Sciences) 100-Talent Program
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/22537]
专题	过程工程研究所_多相复杂系统国家重点实验室
作者单位	1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Beijing Key Lab Ion Liq, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China 3.Henan Univ, Henan Engn Res Ctr Resource & Energy Recovery Was, Coll Chem & Chem Engn, Kaifeng 475004, Peoples R China
推荐引用方式 GB/T 7714	Ren, Tian-Lu,Xu, Bao-Hua,Mahmood, Sajid,et al. Cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds[J]. TETRAHEDRON,2017,73(20):2943-2948.
APA	Ren, Tian-Lu,Xu, Bao-Hua,Mahmood, Sajid,Sun, Ming-Xue,&Zhang, Suo-Jiang.(2017).Cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds.TETRAHEDRON,73(20),2943-2948.
MLA	Ren, Tian-Lu,et al."Cobalt-catalyzed oxidative esterification of allylic/benzylic C(sp(3))-H bonds".TETRAHEDRON 73.20(2017):2943-2948.