K3B3O4(OH)(4)center dot 2H(2)O: A UV Nonlinear Optical Crystal with Isolated [B3O4(OH)(4)](3-) Anion Groups

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	K3B3O4(OH)(4)center dot 2H(2)O: A UV Nonlinear Optical Crystal with Isolated [B3O4(OH)(4)](3-) Anion Groups
	Liu, Q (Liu, Qiong); Zhang, XY (Zhang, Xiangyu); Yang, ZH (Yang, Zhihua); Zhang, FF (Zhang, Fangfang); Liu, LL (Liu, Lili); Han, J (Han, Jian); Li, Z (Li, Zhi); Pan, SL (Pan, Shilie)
刊名	INORGANIC CHEMISTRY
	2016
卷号	55 期号:17 页码:8744-8749
通讯作者	Yang, ZH ; Li, Z ; Pan, SL
英文摘要	A potential ultraviolet (UV) nonlinear optical (NLO) material, K3B3O4(OH)(4)center dot 2H(2)O, was successfully synthesized by hydrothermal methods. The compound crystallizes into the Cmc2(1) space group and exhibits isolated [B3O4(OH)(4)](3-) anion groups connected by O-H center dot center dot center dot O hydrogen bonds. The UV vis diffuse reflectance spectrum shows that K3B3O4(OH)(4)center dot 2H(2)O has a wide transparency range with an absorption edge below 190 nm. Powder second harmonic generation (SHG) measurements using 1064 nm radiation revealed a moderate efficiency, 0.8 X KDP. Additional particle size vs SHG efficiency measurements indicate that K3B3O4(OH)(4)center dot 2H(2)O is type I phase-matchable. Our calculated results show that the borate groups as well as the waters of hydration determine the NLO properties of K3B3O4(OH)(4)center dot 2H(2)O.
收录类别	SCI
WOS记录号	WOS:000382713900058
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/4855]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室新疆理化技术研究所_材料物理与化学研究室
作者单位	1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Liu, Q ,Zhang, XY ,Yang, ZH ,et al. K3B3O4(OH)(4)center dot 2H(2)O: A UV Nonlinear Optical Crystal with Isolated [B3O4(OH)(4)](3-) Anion Groups[J]. INORGANIC CHEMISTRY,2016,55(17):8744-8749.
APA	Liu, Q .,Zhang, XY .,Yang, ZH .,Zhang, FF .,Liu, LL .,...&Pan, SL .(2016).K3B3O4(OH)(4)center dot 2H(2)O: A UV Nonlinear Optical Crystal with Isolated [B3O4(OH)(4)](3-) Anion Groups.INORGANIC CHEMISTRY,55(17),8744-8749.
MLA	Liu, Q ,et al."K3B3O4(OH)(4)center dot 2H(2)O: A UV Nonlinear Optical Crystal with Isolated [B3O4(OH)(4)](3-) Anion Groups".INORGANIC CHEMISTRY 55.17(2016):8744-8749.