Ban+2Znn(BO3)(n)(B2O5)F-n (n=1, 2): new members of the zincoborate fluoride series with two kinds of isolated B-O units

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	Ban+2Znn(BO3)(n)(B2O5)F-n (n=1, 2): new members of the zincoborate fluoride series with two kinds of isolated B-O units
	Mutailipu, M (Mutailipu, Miriding); Su, X (Su, Xin); Zhang, M (Zhang, Min); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
刊名	Inorganic Chemistry Frontiers
	2017
卷号	4 期号:2 页码:281-288
通讯作者	Zhang, M ; Pan, SL
英文摘要	Two new members of zincoborate fluoride series Ban+2Znn(BO3)(n)(B2O5)F-n (n = 1, 2), namely, Ba3Zn(BO3)(B2O5)F and Ba4Zn2(BO3)(2)(B2O5)F-2 were firstly synthesized as high-quality single crystals via a high-temperature solution method by adjusting the molar ratios of reactants. They were structurally determined by single-crystal X-ray diffraction and their structures can be regarded as three dimensional (3D) framework stacking of (2)(infinity)[Zn2B6O16](10-) layers for Ba3Zn(BO3)(B2O5)F and (2)(infinity)[Zn2B4O8O5/2O1/3](17/3-) layers for Ba4Zn2(BO3)(2)(B2O5) F-2. To the best of our knowledge, the two title compounds are the first examples of two kinds of isolated B-O groups that coexist in one zincoborate halide. The structure comparisons were carried out among all the available anhydrous-zincoborates, and it is interesting to conclude that about 80% of zincoborates contain isolated B-O clusters and notably the molar ratio of cation/boron (A/B) affects the polymerization of isolated B-O configuration. What's more, the first-principles calculations, infrared spectra, and UV-vis-NIR diffuse reflectance spectra of title compounds have also been performed.
收录类别	SCI
WOS记录号	WOS:000395802300007
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/4798]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室新疆理化技术研究所_材料物理与化学研究室
作者单位	1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Mutailipu, M ,Su, X ,Zhang, M ,et al. Ban+2Znn(BO3)(n)(B2O5)F-n (n=1, 2): new members of the zincoborate fluoride series with two kinds of isolated B-O units[J]. Inorganic Chemistry Frontiers,2017,4(2):281-288.
APA	Mutailipu, M ,Su, X ,Zhang, M ,Yang, ZH ,&Pan, SL .(2017).Ban+2Znn(BO3)(n)(B2O5)F-n (n=1, 2): new members of the zincoborate fluoride series with two kinds of isolated B-O units.Inorganic Chemistry Frontiers,4(2),281-288.
MLA	Mutailipu, M ,et al."Ban+2Znn(BO3)(n)(B2O5)F-n (n=1, 2): new members of the zincoborate fluoride series with two kinds of isolated B-O units".Inorganic Chemistry Frontiers 4.2(2017):281-288.