Synthesis and characterization of monodisperse spherical core-shell structured SiO2@Y3Al5O12 : Ce3+/Tb3+ phosphors for field emission displays
Liu XM ; Lin J
刊名journal of nanoparticle research
2007
卷号9期号:5页码:869-875
关键词SOL-GEL PROCESS LUMINESCENCE PROPERTIES THIN-FILMS SILICA SPHERES YAG-TB FABRICATION PARTICLES GROWTH Y2O3EU RANGE
ISSN号1388-0764
通讯作者lin j
中文摘要nanocrystalline y3al5o12: ce3+/tb3+ ( average crystalline size 30 nm) phosphor layers were coated on non-aggregated, monodisperse and spherical sio2 particles by the sol-gel method, resulting in the formation of core-shell structured sio2@y3al5o12:ce3+/tb3+ particles. x-ray diffraction, fourier transform infrared spectroscopy, transmission electron microscopy, photoluminescence, cathodoluminescence spectra, as well as lifetimes were utilized to characterize the core-shell structured sio2@y3al5o12: ce3+/tb3+ phosphor particles. the obtained core-shell structured phosphors consist of well-dispersed submicron spherical particles with a narrow size distribution. the thickness of the y3al5o12:ce3+/tb3+ shells on the sio2 cores ( average size about 500 nm, crystalline size about 30 nm) could be easily tailored by varying the number of deposition cycles (100 nm for four deposition cycles). under the excitation of ultraviolet and low-voltage electron beams (1-3 kv), the core-shell sio2@y3al5o12:ce3+/ tb3+ particles show strong yellow-green and green emission corresponding to the 5d-4f emission of ce3+ and d-5(4)-f-7(j) ( j = 6, 5, 4, 3) emission of tb3+, respectively.
收录类别SCI
语种英语
WOS记录号WOS:000247471500017
公开日期2010-07-13
内容类型期刊论文
源URL[http://ir.ciac.jl.cn/handle/322003/13229]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Liu XM,Lin J. Synthesis and characterization of monodisperse spherical core-shell structured SiO2@Y3Al5O12 : Ce3+/Tb3+ phosphors for field emission displays[J]. journal of nanoparticle research,2007,9(5):869-875.
APA Liu XM,&Lin J.(2007).Synthesis and characterization of monodisperse spherical core-shell structured SiO2@Y3Al5O12 : Ce3+/Tb3+ phosphors for field emission displays.journal of nanoparticle research,9(5),869-875.
MLA Liu XM,et al."Synthesis and characterization of monodisperse spherical core-shell structured SiO2@Y3Al5O12 : Ce3+/Tb3+ phosphors for field emission displays".journal of nanoparticle research 9.5(2007):869-875.
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