Important Green Chemistry and Catalysis: Non-phosgene Syntheses of Isocyanates - Thermal Cracking Way | |
Wang PX(王培学)1,2; Liu SM(刘士民)1; Deng YQ(邓友全)1,2 | |
刊名 | Chinese Journal of Chemistry |
2017 | |
卷号 | 35期号:6页码:821-835 |
关键词 | non-phosgene N-substituted carbamates isocyanates carbonylation agent catalysis |
ISSN号 | 1001-604X |
通讯作者 | 邓友全 |
英文摘要 | Currently, industrial production of isocyanates, or diisocyanates in particular, has been exclusively based on phosgene processes. Phosgene is extremely toxic and large amounts of corrosive HCl are produced as a side product. In the view of environment protection and society safety, development of non-phosgene processes for isocyanates production will be highly desired, and this should be one of the most important missions for green chemistry and catalysis. In this review, efforts for development of non-phosgene method for syntheses of isocyanates, i. e., catalytic syntheses of N-substituted carbamates from nitro-or amino-compounds with CO, dimethyl carbonate (DMC), urea and even CO2 etc. as carbonyl sources, then thermal cracking of N-substituted carbamates to afford corresponding isocyanates, are summarized, and a brief prospect for non-phosgene syntheses of isocyanates is also addressed. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (No. 21173240) |
语种 | 英语 |
WOS记录号 | WOS:000404029500006 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/22048] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_固体润滑国家重点实验室 兰州化学物理研究所_青岛研发中心/青岛市资源化学与新材料研究中心 |
作者单位 | 1.Centre for Green and Catalysis, State Key Laboratory for Oxo Synthesis and Selective Oxidation, State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, Gansu 730000, China 2.Qingdao Center of Resource Chemistry & New Materials, Qingdao, Shandong 266100, China |
推荐引用方式 GB/T 7714 | Wang PX,Liu SM,Deng YQ. Important Green Chemistry and Catalysis: Non-phosgene Syntheses of Isocyanates - Thermal Cracking Way[J]. Chinese Journal of Chemistry,2017,35(6):821-835. |
APA | Wang PX,Liu SM,&Deng YQ.(2017).Important Green Chemistry and Catalysis: Non-phosgene Syntheses of Isocyanates - Thermal Cracking Way.Chinese Journal of Chemistry,35(6),821-835. |
MLA | Wang PX,et al."Important Green Chemistry and Catalysis: Non-phosgene Syntheses of Isocyanates - Thermal Cracking Way".Chinese Journal of Chemistry 35.6(2017):821-835. |
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