Kinetic study of formic acid oxidation on carbon supported Pd electrocatalyst | |
Wang YJ ; Wu B ; Gao Y ; Tang YW ; Lu TH ; Xing W ; Liu CP | |
刊名 | journal of power sources
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2009 | |
卷号 | 192期号:2页码:372-375 |
关键词 | PLATINUM-ELECTRODES FUEL-CELLS ELECTROOXIDATION CATALYST NANOPARTICLES BEHAVIOR |
ISSN号 | 0378-7753 |
通讯作者 | gao y |
中文摘要 | the oxidation of formic acid at the pd/c catalyst electrode is a completely irreversible kinetic process with the reaction order of 1.0. the oxidation rate of formic acid is increased with increasing the concentration of formic acid and is decreased with increasing h+ concentration. the apparent negative reaction order with respect to h+ is about -0.18 or -0.04 in h2so4 or hclo4 solution respectively, because bisulfate anions would inhibit formic acid oxidation at some extent. the kinetic parameters, charge transfer coefficient and the diffusion coefficient of formic acid were obtained under the quasi steady-state conditions. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000267270000019 |
公开日期 | 2010-05-04 |
内容类型 | 期刊论文 |
源URL | [http://202.98.16.49/handle/322003/11709] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Wang YJ,Wu B,Gao Y,et al. Kinetic study of formic acid oxidation on carbon supported Pd electrocatalyst[J]. journal of power sources,2009,192(2):372-375. |
APA | Wang YJ.,Wu B.,Gao Y.,Tang YW.,Lu TH.,...&Liu CP.(2009).Kinetic study of formic acid oxidation on carbon supported Pd electrocatalyst.journal of power sources,192(2),372-375. |
MLA | Wang YJ,et al."Kinetic study of formic acid oxidation on carbon supported Pd electrocatalyst".journal of power sources 192.2(2009):372-375. |
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