Kinetic study of formic acid oxidation on carbon supported Pd electrocatalyst

	Kinetic study of formic acid oxidation on carbon supported Pd electrocatalyst
	Wang YJ ; Wu B ; Gao Y ; Tang YW ; Lu TH ; Xing W ; Liu CP
刊名	journal of power sources
	2009
卷号	192 期号:2 页码:372-375
关键词	PLATINUM-ELECTRODES FUEL-CELLS ELECTROOXIDATION CATALYST NANOPARTICLES BEHAVIOR
ISSN号	0378-7753
通讯作者	gao y
中文摘要	the oxidation of formic acid at the pd/c catalyst electrode is a completely irreversible kinetic process with the reaction order of 1.0. the oxidation rate of formic acid is increased with increasing the concentration of formic acid and is decreased with increasing h+ concentration. the apparent negative reaction order with respect to h+ is about -0.18 or -0.04 in h2so4 or hclo4 solution respectively, because bisulfate anions would inhibit formic acid oxidation at some extent. the kinetic parameters, charge transfer coefficient and the diffusion coefficient of formic acid were obtained under the quasi steady-state conditions.
收录类别	SCI
语种	英语
WOS记录号	WOS:000267270000019
公开日期	2010-05-04
内容类型	期刊论文
源URL	[http://202.98.16.49/handle/322003/11709]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Wang YJ,Wu B,Gao Y,et al. Kinetic study of formic acid oxidation on carbon supported Pd electrocatalyst[J]. journal of power sources,2009,192(2):372-375.
APA	Wang YJ.,Wu B.,Gao Y.,Tang YW.,Lu TH.,...&Liu CP.(2009).Kinetic study of formic acid oxidation on carbon supported Pd electrocatalyst.journal of power sources,192(2),372-375.
MLA	Wang YJ,et al."Kinetic study of formic acid oxidation on carbon supported Pd electrocatalyst".journal of power sources 192.2(2009):372-375.