High activity PtRu/C catalysts synthesized by a modified impregnation method for methanol electro-oxidation
Ma L ; Liu CP ; Liao JH ; Lu TH ; Xing W ; Zhang JJ
刊名electrochimica acta
2009
卷号54期号:28页码:7274-7279
关键词PT-RU CATALYSTS PLATINUM-RUTHENIUM NANOPARTICLES FUEL-CELL CARBON NANOTUBES ANODE CATALYST ELECTROCHEMICAL CHARACTERIZATIONS ELECTROCATALYTIC OXIDATION CO ELECTROOXIDATION SPRAY-PYROLYSIS ALLOYS
ISSN号0013-4686
通讯作者xing w
中文摘要a modified impregnation method was used to prepare highly dispersive carbon-supported ptru catalyst (ptru/c). two modifications to the conventional impregnation method were performed: one was to precipitate the precursors ((nh4)(2)ptcl6 and ru(oh)(3)) on the carbon support before metal reduction: the other was to add a buffer into the synthetic solution to stabilize the ph. the prepared catalyst showed a much higher activity for methanol electro-oxidation than a catalyst prepared by the conventional impregnation method. even higher than that of current commercially available, state-of-the-art catalysts. the morphology of the prepared catalyst was characterized using tem and xrd measurements to determine particle sizes, alloying degree, and lattice parameters. electrochemical methods were also used to ascertain the electrochemical active surface area and the specific activity of the catalyst.
收录类别SCI
语种英语
WOS记录号WOS:000271151600016
公开日期2010-05-04
内容类型期刊论文
源URL[http://202.98.16.49/handle/322003/11693]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Ma L,Liu CP,Liao JH,et al. High activity PtRu/C catalysts synthesized by a modified impregnation method for methanol electro-oxidation[J]. electrochimica acta,2009,54(28):7274-7279.
APA Ma L,Liu CP,Liao JH,Lu TH,Xing W,&Zhang JJ.(2009).High activity PtRu/C catalysts synthesized by a modified impregnation method for methanol electro-oxidation.electrochimica acta,54(28),7274-7279.
MLA Ma L,et al."High activity PtRu/C catalysts synthesized by a modified impregnation method for methanol electro-oxidation".electrochimica acta 54.28(2009):7274-7279.
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