Synthesis and characterization of functional poly(gamma-benzyl-L-glutamate) (PBLG) as a hydrophobic precursor

	Synthesis and characterization of functional poly(gamma-benzyl-L-glutamate) (PBLG) as a hydrophobic precursor
	Guo JS ; Huang YB ; Jing XB ; Chen XS
刊名	polymer
	2009
卷号	50 期号:13 页码:2847-2855
关键词	CHOLESTERIC MESOPHASE PROPERTIES CLICK-CHEMISTRY THERMOTROPIC POLYPEPTIDES L-GLUTAMATE TRIBLOCK COPOLYMER SIDE-CHAINS L-GLUTAMATE) POLYMERS DERIVATIVES ACID
ISSN号	0032-3861
通讯作者	huang yb
中文摘要	four kinds of functional poly(gamma-benzyl-l-glutamate) (pblg) copolymers containing chloro, azido, allyl or propargyl groups on the side chains were synthesized through ester exchange reactions of pblg with functional alcohols without any protection and de-protection process. hydrolysis of pblg, which was found during the ester exchange reaction under low ratios of alcohol to the repeat units of pblg, was thoroughly investigated, and could be successfully depressed by addition of certain amount of benzyl alcohol to the reaction system. click chemistry reactions of the azidized or propargylated copolymers, thiol-ene reaction of the allyllated copolymer were taken successfully, indicating that the functional groups on the copolymers were still reactive.
收录类别	SCI
语种	英语
WOS记录号	WOS:000267415600015
公开日期	2010-05-04
内容类型	期刊论文
源URL	[http://202.98.16.49/handle/322003/11573]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Guo JS,Huang YB,Jing XB,et al. Synthesis and characterization of functional poly(gamma-benzyl-L-glutamate) (PBLG) as a hydrophobic precursor[J]. polymer,2009,50(13):2847-2855.
APA	Guo JS,Huang YB,Jing XB,&Chen XS.(2009).Synthesis and characterization of functional poly(gamma-benzyl-L-glutamate) (PBLG) as a hydrophobic precursor.polymer,50(13),2847-2855.
MLA	Guo JS,et al."Synthesis and characterization of functional poly(gamma-benzyl-L-glutamate) (PBLG) as a hydrophobic precursor".polymer 50.13(2009):2847-2855.