Electrodeposition of platinum nanoclusters on type I collagen modified electrode and its electrocatalytic activity for methanol oxidation | |
Sun YJ ; Sun LL ; Xu FG ; Guo CL ; Liu ZL ; Zhang Y ; Yang T ; Li Z | |
刊名 | applied surface science |
2009 | |
卷号 | 255期号:15页码:6814-6818 |
关键词 | CARBON NANOTUBES FUEL-CELLS NANOPARTICLES SURFACE DEPOSITION NANOWIRES FILM CATALYSIS TEMPLATE FIBER |
ISSN号 | 0169-4332 |
通讯作者 | li z |
中文摘要 | we firstly reported a novel polymer matrix fabricated by type i collagen and polymers, and this matrix can be used as nanoreactors for electrodepositing platinum nanoclusters (pncs). the type i collagen film has a significant effect on the growth of pncs. the size of the platinum nanoparticles could be readily tuned by adjusting deposition time, potential and the concentration of electrolyte, which have been verified by field-emitted scanning electron microscopy (fe-sem). furthermore, cyclic voltammetry (cv) has demonstrated that the as-prepared pncs can catalyze methanol directly with higher activity than that prepared on pss/pdda film, and with better tolerance to poisoning than the commercial e-tek catalyst. the collagen-polymer matrix can be used as a general reactor to electrodeposit other metal nanostructures. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000265906300012 |
公开日期 | 2010-05-04 |
内容类型 | 期刊论文 |
源URL | [http://202.98.16.49/handle/322003/11435] |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Sun YJ,Sun LL,Xu FG,et al. Electrodeposition of platinum nanoclusters on type I collagen modified electrode and its electrocatalytic activity for methanol oxidation[J]. applied surface science,2009,255(15):6814-6818. |
APA | Sun YJ.,Sun LL.,Xu FG.,Guo CL.,Liu ZL.,...&Li Z.(2009).Electrodeposition of platinum nanoclusters on type I collagen modified electrode and its electrocatalytic activity for methanol oxidation.applied surface science,255(15),6814-6818. |
MLA | Sun YJ,et al."Electrodeposition of platinum nanoclusters on type I collagen modified electrode and its electrocatalytic activity for methanol oxidation".applied surface science 255.15(2009):6814-6818. |
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