Well-defined higher-molecular-weight polyacrylonitrile via RAFT technique in the presence of disulfide compounds as a source of chain transfer agent

	Well-defined higher-molecular-weight polyacrylonitrile via RAFT technique in the presence of disulfide compounds as a source of chain transfer agent
	Liu XH ; Zhang GB ; Li BX ; Bai YG ; Pan D ; Li YS
刊名	european polymer journal
	2008
卷号	44 期号:4 页码:1200-1208
关键词	FREE-RADICAL POLYMERIZATION TERMINATION RATE COEFFICIENTS LENGTH-DEPENDENT TERMINATION METHYL ACRYLATE ACRYLONITRILE DITHIOBENZOATE POLYMERS KINETICS STYRENE ACCESS
ISSN号	0014-3057
通讯作者	li ys
中文摘要	well-defined polyacrylonitrile with a higher number-average molecular weight (r.) up to 200,000 and a lower polydispersity index (pdi, 1.7-2.0) was firstly obtained via reversible addition-fragmentation chain transfer (raft) process. this was achieved by selecting a stable, easy way to prepare disulfide compound intermediates including bis(thiobenzoyl) disulfide (btbds) and bis(thiophenylacetoyl) disulfide (btpads) to react with azobis(isobutyronitrile) to directly synthesize raft agents in situ.
收录类别	SCI
语种	英语
WOS记录号	WOS:000255625600026
公开日期	2010-04-14
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/10879]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Liu XH,Zhang GB,Li BX,et al. Well-defined higher-molecular-weight polyacrylonitrile via RAFT technique in the presence of disulfide compounds as a source of chain transfer agent[J]. european polymer journal,2008,44(4):1200-1208.
APA	Liu XH,Zhang GB,Li BX,Bai YG,Pan D,&Li YS.(2008).Well-defined higher-molecular-weight polyacrylonitrile via RAFT technique in the presence of disulfide compounds as a source of chain transfer agent.european polymer journal,44(4),1200-1208.
MLA	Liu XH,et al."Well-defined higher-molecular-weight polyacrylonitrile via RAFT technique in the presence of disulfide compounds as a source of chain transfer agent".european polymer journal 44.4(2008):1200-1208.