Well-defined higher-molecular-weight polyacrylonitrile via RAFT technique in the presence of disulfide compounds as a source of chain transfer agent | |
Liu XH ; Zhang GB ; Li BX ; Bai YG ; Pan D ; Li YS | |
刊名 | european polymer journal
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2008 | |
卷号 | 44期号:4页码:1200-1208 |
关键词 | FREE-RADICAL POLYMERIZATION TERMINATION RATE COEFFICIENTS LENGTH-DEPENDENT TERMINATION METHYL ACRYLATE ACRYLONITRILE DITHIOBENZOATE POLYMERS KINETICS STYRENE ACCESS |
ISSN号 | 0014-3057 |
通讯作者 | li ys |
中文摘要 | well-defined polyacrylonitrile with a higher number-average molecular weight (r.) up to 200,000 and a lower polydispersity index (pdi, 1.7-2.0) was firstly obtained via reversible addition-fragmentation chain transfer (raft) process. this was achieved by selecting a stable, easy way to prepare disulfide compound intermediates including bis(thiobenzoyl) disulfide (btbds) and bis(thiophenylacetoyl) disulfide (btpads) to react with azobis(isobutyronitrile) to directly synthesize raft agents in situ. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000255625600026 |
公开日期 | 2010-04-14 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/10879] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Liu XH,Zhang GB,Li BX,et al. Well-defined higher-molecular-weight polyacrylonitrile via RAFT technique in the presence of disulfide compounds as a source of chain transfer agent[J]. european polymer journal,2008,44(4):1200-1208. |
APA | Liu XH,Zhang GB,Li BX,Bai YG,Pan D,&Li YS.(2008).Well-defined higher-molecular-weight polyacrylonitrile via RAFT technique in the presence of disulfide compounds as a source of chain transfer agent.european polymer journal,44(4),1200-1208. |
MLA | Liu XH,et al."Well-defined higher-molecular-weight polyacrylonitrile via RAFT technique in the presence of disulfide compounds as a source of chain transfer agent".european polymer journal 44.4(2008):1200-1208. |
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