Synthesis of stable arsonium and sulfur ylides from perfluoroalkanesulfonyl diazocarbonyl compounds and their X-ray diffraction analysis | |
Pang W(庞婉) ; Zhu SF(祝诗发) ; Xing CH(邢春晖) ; Luo NH(罗年华) ; Jiang HF(蒋焕峰) ; Zhu SZ(朱仕正) | |
刊名 | J. Fluor. Chem.
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2008 | |
卷号 | 129期号:5页码:343-348 |
ISSN号 | 0022-1139 |
其他题名 | Synthesis of stable arsonium and sulfur ylides from perfluoroalkanesulfonyl diazocarbonyl compounds and their X-ray diffraction analysis |
通讯作者 | 蒋焕峰 ; 朱仕正 |
英文摘要 | A series of stable fluorine-containing arsonium ylides and sulfur ylides were simply synthesized from perfluoroalkanesulfonyl diazocarbonyl compounds in the presence of rhodium catalyst. The ylide products are fairly stable due to the strong electron-withdrawing properties of perfluoroalkanesulfonyl group and carbonyl group. They are fully confirmed by spectral methods and the structures of 3ba and 3cd are also established by X-ray single crystal diffraction analysis. Several interesting features about the ylide structures and some weak fluorine interaction between them are described here. (c) 2008 Elsevier B.V. All rights reserved. |
学科主题 | 有机氟化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1016/j.jfluchem.2008.01.007 |
语种 | 英语 |
WOS记录号 | WOS:000255990600004 |
公开日期 | 2013-01-18 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/14448] ![]() |
专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
推荐引用方式 GB/T 7714 | Pang W,Zhu SF,Xing CH,et al. Synthesis of stable arsonium and sulfur ylides from perfluoroalkanesulfonyl diazocarbonyl compounds and their X-ray diffraction analysis[J]. J. Fluor. Chem.,2008,129(5):343-348. |
APA | 庞婉,祝诗发,邢春晖,罗年华,蒋焕峰,&朱仕正.(2008).Synthesis of stable arsonium and sulfur ylides from perfluoroalkanesulfonyl diazocarbonyl compounds and their X-ray diffraction analysis.J. Fluor. Chem.,129(5),343-348. |
MLA | 庞婉,et al."Synthesis of stable arsonium and sulfur ylides from perfluoroalkanesulfonyl diazocarbonyl compounds and their X-ray diffraction analysis".J. Fluor. Chem. 129.5(2008):343-348. |
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