A new route to fluorine-containing aziridines and α-amino esters | |
Xu Y(许勇) ; Zhu SZ(朱仕正) | |
刊名 | Tetrahedron
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2001 | |
卷号 | 57期号:4页码:669-674 |
ISSN号 | 0040-4020 |
其他题名 | 一种合成含氟的α-氨基酸酯和氮杂三元环的新方法 |
通讯作者 | 朱仕正 |
英文摘要 | The reaction of fluoroalkanesulfonyl azides with several sily ketene acetals has been investigated. 1-Ethoxyl-1-trimethylsilyl-oxy-ethylene reacted readily with azides to afford N-fluoroalkanesulfonyl substituted glycinates in good yields. However, reaction of monoor dialkyl-substituted silyl ketene acetals wit azides gave rise to N-substituted α-amino esters and substituted N-perfluoroalkanesulfonyl aziridines. Acidic hydrolysis of the aziridines was also investigated. Mechanisms for the formation of the formation of the aziridines and α-amino esters are discussed. |
学科主题 | 有机氟化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1016/S0040-4020(00)01050-4 |
语种 | 英语 |
公开日期 | 2013-01-18 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/14246] ![]() |
专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
推荐引用方式 GB/T 7714 | Xu Y,Zhu SZ. A new route to fluorine-containing aziridines and α-amino esters[J]. Tetrahedron,2001,57(4):669-674. |
APA | 许勇,&朱仕正.(2001).A new route to fluorine-containing aziridines and α-amino esters.Tetrahedron,57(4),669-674. |
MLA | 许勇,et al."A new route to fluorine-containing aziridines and α-amino esters".Tetrahedron 57.4(2001):669-674. |
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