A new route to fluorine-containing aziridines and α-amino esters
Xu Y(许勇) ; Zhu SZ(朱仕正)
刊名Tetrahedron
2001
卷号57期号:4页码:669-674
ISSN号0040-4020
其他题名一种合成含氟的α-氨基酸酯和氮杂三元环的新方法
通讯作者朱仕正
英文摘要The reaction of fluoroalkanesulfonyl azides with several sily ketene acetals has been investigated. 1-Ethoxyl-1-trimethylsilyl-oxy-ethylene reacted readily with azides to afford N-fluoroalkanesulfonyl substituted glycinates in good yields. However, reaction of monoor dialkyl-substituted silyl ketene acetals wit azides gave rise to N-substituted α-amino esters and substituted N-perfluoroalkanesulfonyl aziridines. Acidic hydrolysis of the aziridines was also investigated. Mechanisms for the formation of the formation of the aziridines and α-amino esters are discussed.
学科主题有机氟化学
收录类别SCI
原文出处http://dx.doi.org/10.1016/S0040-4020(00)01050-4
语种英语
公开日期2013-01-18
内容类型期刊论文
源URL[http://202.127.28.38/handle/331003/14246]  
专题上海有机化学研究所_中科院有机氟化学重点实验室
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Xu Y,Zhu SZ. A new route to fluorine-containing aziridines and α-amino esters[J]. Tetrahedron,2001,57(4):669-674.
APA 许勇,&朱仕正.(2001).A new route to fluorine-containing aziridines and α-amino esters.Tetrahedron,57(4),669-674.
MLA 许勇,et al."A new route to fluorine-containing aziridines and α-amino esters".Tetrahedron 57.4(2001):669-674.
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