An enantio selective nucleophilic addition of alpha, beta-unsaturated trifluoromethylketones catalyzed by L-proline derivatives

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	An enantio selective nucleophilic addition of alpha, beta-unsaturated trifluoromethylketones catalyzed by L-proline derivatives
	Zhang DH(张德晖) ; Yuan CY(袁承业)
刊名	Tetrahedron
	2008
卷号	64 期号:10 页码:2480-2488
ISSN号	0040-4020
其他题名	L-辅氨酸衍生物催化的α,β-不饱和三氟甲基酮的对映选择亲核加成反应
英文摘要	An unexpected enantioselective 1,2-aldol reaction of acetone with alpha, beta-unsaturated trifluoromethylketone catalyzed by L-proline derivative was described. The absolute configuration of the resulting chiral product was assigned based on a single crystal X-ray diffraction analysis. Structure-reactivity study of this organocatalytic system was briefly discussed. A reaction mechanism was tentatively postulated. (C) 2007 Elsevier Ltd. All rights reserved.
学科主题	元素有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.tet.2007.12.035
语种	英语
WOS记录号	WOS:000253432600023
公开日期	2013-01-09
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/11076]
专题	上海有机化学研究所_上海有机化学研究所
推荐引用方式 GB/T 7714	Zhang DH,Yuan CY. An enantio selective nucleophilic addition of alpha, beta-unsaturated trifluoromethylketones catalyzed by L-proline derivatives[J]. Tetrahedron,2008,64(10):2480-2488.
APA	张德晖,&袁承业.(2008).An enantio selective nucleophilic addition of alpha, beta-unsaturated trifluoromethylketones catalyzed by L-proline derivatives.Tetrahedron,64(10),2480-2488.
MLA	张德晖,et al."An enantio selective nucleophilic addition of alpha, beta-unsaturated trifluoromethylketones catalyzed by L-proline derivatives".Tetrahedron 64.10(2008):2480-2488.