A novel and convenient synthetic method for producing α-(trifluoromethyl)styrenes (3)

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	A novel and convenient synthetic method for producing α-(trifluoromethyl)styrenes (3)
	Pan RQ(潘瑞琪) ; Liu XX(刘新兴) ; Deng MZ(邓敏智)
刊名	J. Fluor. Chem.
	1999
卷号	95 页码:167-170
ISSN号	0022-1139
其他题名	一个新型方便地生成α－三氟甲基苯乙烯的方法
通讯作者	邓敏智
英文摘要	The suzuki-type coupling reaction of arylboronic acids (1) with 2-bromo-3,3,3-trifluoropropene (2) in the presence of a catalytic amount of dichlorobis(triphenylphosphine)palladium {PdCl=2(PPh=3)=2} and a base can easily give α-(trifluoromethyl)styrenes (3) in good yields. It was also found that 1,2-dibromo-3,3,3-trifluoropropane (4) underwent dehydrobromination in the presence of KOH, and subsequently, palladium-catalyzed cross-coupling with 1 to directly afford 3 in a one pot manner in excellent yields.
学科主题	有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/S0022-1139(99)00021-4
语种	英语
公开日期	2013-03-07
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/23074]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Pan RQ,Liu XX,Deng MZ. A novel and convenient synthetic method for producing α-(trifluoromethyl)styrenes (3)[J]. J. Fluor. Chem.,1999,95:167-170.
APA	潘瑞琪,刘新兴,&邓敏智.(1999).A novel and convenient synthetic method for producing α-(trifluoromethyl)styrenes (3).J. Fluor. Chem.,95,167-170.
MLA	潘瑞琪,et al."A novel and convenient synthetic method for producing α-(trifluoromethyl)styrenes (3)".J. Fluor. Chem. 95(1999):167-170.