Thermolytic products derived from thermolysis of cycloolefin-coordinated diiron bridging carbene complexes

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	Thermolytic products derived from thermolysis of cycloolefin-coordinated diiron bridging carbene complexes
	Zhang L(张磊) ; Sun J(孙杰) ; Zhu HP(朱沪平) ; 津森展子 ; Xu Q(徐强) ; Chen JB(陈家碧)
刊名	Organometallics
	2007
卷号	26 期号:10 页码:2630-2636
ISSN号	0276-7333
其他题名	Thermolytic products derived from thermolysis of cycloolefin-coordinated diiron bridging carbene complexes
通讯作者	陈家碧
英文摘要	Heating a benzene solution of the COT-coordinated diiron bridging alkoxycarbene complexes [Fe-2{mu-C(OC2H5)Ar}(CO)(4)(eta(8)-C8H8)] (1, Ar = C6H5; 2, Ar = p-CH3C6H4; 3, Ar = p-CF3C6H4) in a sealed tube at 85-90 degrees C for 72 h gave the bicycloolefin-coordinated tricarbonyliron dimers [Fe{eta(4)-C9H8(Ar}(CO)(3)](2) (10, Ar = C6H5; 12, Ar = p-CH3C6H4; 14, Ar = p-CF3C6H4) and bridging arylcarbene complexes [Fe-2{mu-C(H)Ar}(CO)(4)(eta(8)-C8H8)] (11, Ar = C6H5; 13, Ar = p-CH3C6H4; 15, Ar = p-CF3C6H4). A similar thermolysis of 7H-indene-coordinated diiron bridging alkoxycarbene complex [Fe-2{mu-C(OC2H5)C6H5}(CO)(4)(eta(4),eta(4)-C9H8)] (4) yielded the ring addition product [Fe-2{C(OC2H5)C6H5(eta(2),eta(5)-C9H8)}(CO)(5)] (16). The 7H-indene-coordinated diiron bridging arylthiocarbene complexes [Fe-2{mu-C(Ar)SC6H4CH3-p}(CO)(4)(eta(4),eta(4)-C9H8)] (8, Ar = C6H5; 9, Ar = p-C6H5C6H4) were heated similarly to afford the isomerized 7H-indene-coordinated diiron bridging carbene complexes with a mu-SC6H4CH3-p ligand, [Fe-2{mu-C(Ar)(eta(2),eta(5)-C9H8)}(mu-SC6H4CH3-p)(CO)(3)] (17, Ar = C6H5; 19, Ar = p-C6H5C6H4), and the acyliron compounds [Fe(CO)(2)(CO){C(H)Ar(eta(5)-C9H8)}] (18, Ar = C6H5; 20, Ar = p-C6H5C6H4). The structures of complexes 14, 16, 17, and 18 have been established by X-ray diffraction studies.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/om070009a
语种	英语
WOS记录号	WOS:000246027300024
公开日期	2013-02-27
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/21419]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Zhang L,Sun J,Zhu HP,et al. Thermolytic products derived from thermolysis of cycloolefin-coordinated diiron bridging carbene complexes[J]. Organometallics,2007,26(10):2630-2636.
APA	张磊,孙杰,朱沪平,津森展子,徐强,&陈家碧.(2007).Thermolytic products derived from thermolysis of cycloolefin-coordinated diiron bridging carbene complexes.Organometallics,26(10),2630-2636.
MLA	张磊,et al."Thermolytic products derived from thermolysis of cycloolefin-coordinated diiron bridging carbene complexes".Organometallics 26.10(2007):2630-2636.