Synthesis of single and double butterfly iron caronyl complexes by reactions of[(μRSe)(μ-CO)Fe^2(CO)^6]anions. Crystal structures of （μp-MeC^6H^4Se)[μ-PhCH^2N(H)C=S]Fe^2(CO)^6 and [(μ-PhSe)(μ-MeAs)Fe^2(CO)^6]^2

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	Synthesis of single and double butterfly iron caronyl complexes by reactions of[(μRSe)(μ-CO)Fe^2(CO)^6]anions. Crystal structures of （μp-MeC^6H^4Se)[μ-PhCH^2N(H)C=S]Fe^2(CO)^6 and [(μ-PhSe)(μ-MeAs)Fe^2(CO)^6]^2
	宋礼诚 ; Guo-Liang Lu ; Qing-Mei Hu ; Hong-Tao Fan ; 陈家碧 ; 孙杰 ; Xiao-Ying Huang
刊名	J. Organomet. Chem.
	2001
卷号	627 页码:255-262
ISSN号	0022-328X
其他题名	通过[(μRSe)(μ-CO)Fe^2(CO)^6]阴离子的反应合成单和双蝶铁羰基络合物。(μp-MeC^6H^4Se)[μ-PhCH^2N(H)C=S]Fe^2(CO)^6 and [(μ-PhSe)(μ-MeAs)Fe^2(CO)^6]^2
通讯作者	宋礼诚
英文摘要	The in situ reactions of the [Et^3NH]+ AND [MgBr]+ salts of [(μRSe)(μ-CO)Fe^2(CO)^6] -(1) Anions with PhC(Cl)=NPh gave single butterfly complexes [(μRSe)(μ-PhC=NPhFe(CO)^6 (2, R=Ph; 3 R=p-MeC^6H^4; 4, R=Et), whereas those of the [Et^3NH]+salts of 1 with R'N=C=Safforded single butterfly complexes (μRSe)[μ-R'N(H)C=S]Fe^2(CO)^6(5,R=Ph,R'=Ph;6,R=p-MeC^6H^4R'=Ph;7R=p-MeC^6H^4,R'=PhCO;8,R=p-MeC^6H^4,R=PhCH^2). Compound 8 could also be prepared by reaction of the [MgBr]+ salt of 1 R=p-MeC^6H^4) with PhCH^2NCS followed by treatment with CF^3CO^2H. More interestingly, while the [Et^3NH]+ salt of 1 (R=Ph) reacted with Et^3OBF^4 to give a carbyne ligand-bridged single butterfly complex μ-PhSe)(μEtOC)Fe^2(CO)^6(9), reaction of the [Et^3NH]+salt of 1(R=Ph)with MeAsI^@ PRODUCED A MeAs-AsMe ligand-bridged double butterfly complex [(μ-PhSe)(μ-MeAs)Fe^2(CO)^6]^2 (10). All the new complexes, 2-10, were characterized by elemental analysis and various spectroscopic methods, for complexes 8 and 10, the structures were also confirmed by X-ray diffraction techniques.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/S0022-328X(01)00766-5
语种	英语
公开日期	2013-02-27
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/21379]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	宋礼诚,Guo-Liang Lu,Qing-Mei Hu,等. Synthesis of single and double butterfly iron caronyl complexes by reactions of[(μRSe)(μ-CO)Fe^2(CO)^6]anions. Crystal structures of （μp-MeC^6H^4Se)[μ-PhCH^2N(H)C=S]Fe^2(CO)^6 and [(μ-PhSe)(μ-MeAs)Fe^2(CO)^6]^2[J]. J. Organomet. Chem.,2001,627:255-262.
APA	宋礼诚.,Guo-Liang Lu.,Qing-Mei Hu.,Hong-Tao Fan.,陈家碧.,...&Xiao-Ying Huang.(2001).Synthesis of single and double butterfly iron caronyl complexes by reactions of[(μRSe)(μ-CO)Fe^2(CO)^6]anions. Crystal structures of （μp-MeC^6H^4Se)[μ-PhCH^2N(H)C=S]Fe^2(CO)^6 and [(μ-PhSe)(μ-MeAs)Fe^2(CO)^6]^2.J. Organomet. Chem.,627,255-262.
MLA	宋礼诚,et al."Synthesis of single and double butterfly iron caronyl complexes by reactions of[(μRSe)(μ-CO)Fe^2(CO)^6]anions. Crystal structures of （μp-MeC^6H^4Se)[μ-PhCH^2N(H)C=S]Fe^2(CO)^6 and [(μ-PhSe)(μ-MeAs)Fe^2(CO)^6]^2".J. Organomet. Chem. 627(2001):255-262.