Remarkable reactions of cationic carbyne complexes of manganese and rhenium with Na[Fe(CO)=4CN and Et=4N[Mn(CO)=4(CN)2]

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	Remarkable reactions of cationic carbyne complexes of manganese and rhenium with Na[Fe(CO)=4CN and Et=4N[Mn(CO)=4(CN)2]
	Tang YJ(唐拥军) ; Sun J(孙杰) ; Chen JB(陈家碧)
刊名	Organometallics
	1999
卷号	18 页码:4337-4343
ISSN号	0276-7333
其他题名	锰和铼阳离子卡拜络合物与Na[Fe(CO)=4CN和Et=4N[Mn(CO)=4(CN)2]
通讯作者	陈家碧
英文摘要	The reaction of a cationic carbyne complex of manganese, [(η－C=5H5)(CO)=2Mn≡CC=6H=5]BBr=4(1), with Na[Fe(CO)=4CN] (3) in THF at low temperature gives the phenyl(tetracarbonylcyanoiron)carbene-manganese complex[{η-C=5H=5}(CO)=2Mn=C(C=6C=5)NCFe(CO)=4](5). The analogous reaction of a cationic carbyne complex of rhenium, [(η-C=5H=5(CO)2Re≡CC=6H=5)BBr=4(2),with 3 affords the corresponding carbene-rhenium complex[(η-C=5H=5)(CO)=2Re=C(C=6H=5)NCFe-(CO)=4](6). Complex 1 reacts with Et=4N[Mn(CO)=4(CN)=2](4) to yield the noveltrinuclear metal dicarbene-manganese complex[{(η-C=5H=5)(CO)=2Mn=C(C=6H=5)NC}=2Mn (CO)=3CN](7) and the novel tetranuclear metal dicarbene-manganese complex[{(η-C=5H=5)(CO)=2Mn =C(C=6H=5)NC}=2Mn(CO)=3CNMn(CO)2 (η-C=5H=5)] (8). Complex 2 reacts similarly with 4 to afford the corresponding trinuclear dicarbene-rhenium complex [{(η-C=5H=5)(CO)=2 Re=C(C=6H=5)NC}=2Mn-(CO)=3CN] (9). The structures of complexes 5-9 have been established by X-ray crystallography.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/om990431u
语种	英语
公开日期	2013-02-27
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/21365]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Tang YJ,Sun J,Chen JB. Remarkable reactions of cationic carbyne complexes of manganese and rhenium with Na[Fe(CO)=4CN and Et=4N[Mn(CO)=4(CN)2][J]. Organometallics,1999,18:4337-4343.
APA	唐拥军,孙杰,&陈家碧.(1999).Remarkable reactions of cationic carbyne complexes of manganese and rhenium with Na[Fe(CO)=4CN and Et=4N[Mn(CO)=4(CN)2].Organometallics,18,4337-4343.
MLA	唐拥军,et al."Remarkable reactions of cationic carbyne complexes of manganese and rhenium with Na[Fe(CO)=4CN and Et=4N[Mn(CO)=4(CN)2]".Organometallics 18(1999):4337-4343.