Synergistic effect of binary component ligands in chiral catalyst library engineering for enantioselective reactions | |
Ding KL(丁奎岭) | |
刊名 | Chem. Commun.
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2008 | |
期号 | 8页码:909-921 |
ISSN号 | 1359-7345 |
其他题名 | Synergistic effect of binary component ligands in chiral catalyst library engineering for enantioselective reactions |
英文摘要 | This article highlights our recent efforts in the development of highly efficient and cost-effective chiral catalysts for asymmetric reactions through a combinatorial approach by assembling the component ligands ( at least one of which is in non-racemic form, while the other might be optically pure, racemic or achiral) with metal ions to generate modular chiral catalyst libraries. The synergistic effect of the binary ligands in terms of both enantioselectivity and activity of the catalysis has been observed in a variety of catalyst systems, including catalysts containing Ti(IV), Zn(II), Rh(I) or Ru(II) ions, for asymmetric hetero-Diels-Alder, carbonyl-ene, alkylation, and hydrogenation reactions, respectively. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1039/b710668h |
语种 | 英语 |
WOS记录号 | WOS:000253249600001 |
公开日期 | 2013-02-22 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/17851] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Ding KL. Synergistic effect of binary component ligands in chiral catalyst library engineering for enantioselective reactions[J]. Chem. Commun.,2008(8):909-921. |
APA | 丁奎岭.(2008).Synergistic effect of binary component ligands in chiral catalyst library engineering for enantioselective reactions.Chem. Commun.(8),909-921. |
MLA | 丁奎岭."Synergistic effect of binary component ligands in chiral catalyst library engineering for enantioselective reactions".Chem. Commun. .8(2008):909-921. |
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