Synergistic effect of binary component ligands in chiral catalyst library engineering for enantioselective reactions
Ding KL(丁奎岭)
刊名Chem. Commun.
2008
期号8页码:909-921
ISSN号1359-7345
其他题名Synergistic effect of binary component ligands in chiral catalyst library engineering for enantioselective reactions
英文摘要This article highlights our recent efforts in the development of highly efficient and cost-effective chiral catalysts for asymmetric reactions through a combinatorial approach by assembling the component ligands ( at least one of which is in non-racemic form, while the other might be optically pure, racemic or achiral) with metal ions to generate modular chiral catalyst libraries. The synergistic effect of the binary ligands in terms of both enantioselectivity and activity of the catalysis has been observed in a variety of catalyst systems, including catalysts containing Ti(IV), Zn(II), Rh(I) or Ru(II) ions, for asymmetric hetero-Diels-Alder, carbonyl-ene, alkylation, and hydrogenation reactions, respectively.
学科主题金属有机化学
收录类别SCI
原文出处http://dx.doi.org/10.1039/b710668h
语种英语
WOS记录号WOS:000253249600001
公开日期2013-02-22
内容类型期刊论文
源URL[http://202.127.28.38/handle/331003/17851]  
专题上海有机化学研究所_金属有机化学国家重点实验室
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Ding KL. Synergistic effect of binary component ligands in chiral catalyst library engineering for enantioselective reactions[J]. Chem. Commun.,2008(8):909-921.
APA 丁奎岭.(2008).Synergistic effect of binary component ligands in chiral catalyst library engineering for enantioselective reactions.Chem. Commun.(8),909-921.
MLA 丁奎岭."Synergistic effect of binary component ligands in chiral catalyst library engineering for enantioselective reactions".Chem. Commun. .8(2008):909-921.
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