Synthesis of dendritic schiff base ligands for titanium catalyzed enantioselective HAD reaction of danishelfsky's diene with aldehydes

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	Synthesis of dendritic schiff base ligands for titanium catalyzed enantioselective HAD reaction of danishelfsky's diene with aldehydes
	Ji BM(吉保明) ; Ding KL(丁奎岭) ; Meng JB(孟继本)
刊名	Chin. J. Chem.
	2003
卷号	21 期号:7 页码:727-730
ISSN号	1001-604X
其他题名	树枝状希夫碱配体的合成及其钛络合物催化的Danishelfsky's二烯与醛的杂D-A反应
通讯作者	丁奎岭
英文摘要	A new type of dendritic NOBIN derived schiff base hgands has been synthesized and applied to titanium catalyzed hetero-diels alder reaction of danishelfsky's diene and aldehydes, affording the corresponding 2-substituted 2,3-dihydro-4H-pyran-4-one in good yields and moderate enantioselectivites (up to 59.2% ee). It was found that the size of dendron attached to the tridentated ligands has slight impact on the enantioselectivity of the reaction and the second generation of dendritic ligand exhibited the best enantioselectivity.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/cjoc.20030210705
语种	英语
公开日期	2013-02-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/17753]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Ji BM,Ding KL,Meng JB. Synthesis of dendritic schiff base ligands for titanium catalyzed enantioselective HAD reaction of danishelfsky's diene with aldehydes[J]. Chin. J. Chem.,2003,21(7):727-730.
APA	吉保明,丁奎岭,&孟继本.(2003).Synthesis of dendritic schiff base ligands for titanium catalyzed enantioselective HAD reaction of danishelfsky's diene with aldehydes.Chin. J. Chem.,21(7),727-730.
MLA	吉保明,et al."Synthesis of dendritic schiff base ligands for titanium catalyzed enantioselective HAD reaction of danishelfsky's diene with aldehydes".Chin. J. Chem. 21.7(2003):727-730.