Synthesis of 2-Methylindoline- and 2-Methyl-1,2,3,4-tetrahydroquinoline-Derived Phosphoramidites and Their Applications in Iridium-Catalyzed Allylic Alkylation of Indoles

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 金属有机化学国家重点实验室

	Synthesis of 2-Methylindoline- and 2-Methyl-1,2,3,4-tetrahydroquinoline-Derived Phosphoramidites and Their Applications in Iridium-Catalyzed Allylic Alkylation of Indoles
	Liu WB(刘文博) ; He H(贺虎) ; Dai LX(戴立信) ; You SL(游书力)
刊名	Synthesis
	2009
期号	12 页码:2076-2082
ISSN号	0039-7881
其他题名	基于2-甲基吲哚啉和2-甲基-1,2,3,4-四氢喹啉的氮磷配体的合成及应用:铱催化下吲哚类化合物的烯丙基烷基化
通讯作者	游书力
英文摘要	A series of novel phosphoramidite ligands were synthesized from enantiopure BINOL and 2-methylindoline or 2-methyl-1,2,3,4-tetrahydroquinoline. These ligands were found to be efficient in iridium-catalyzed Friedel-Crafts reaction of indoles with allylic carbonates, affording branched products with high regio- and enantioselectivities. Strikingly, these ligands were demonstrated to be superior to the Feringa ligands when the ortho-substituted cinnamyl carbonates were used.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1055/s-0029-1216823
语种	英语
WOS记录号	WOS:000267668800021
公开日期	2013-02-19
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/15985]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Liu WB,He H,Dai LX,et al. Synthesis of 2-Methylindoline- and 2-Methyl-1,2,3,4-tetrahydroquinoline-Derived Phosphoramidites and Their Applications in Iridium-Catalyzed Allylic Alkylation of Indoles[J]. Synthesis,2009(12):2076-2082.
APA	刘文博,贺虎,戴立信,&游书力.(2009).Synthesis of 2-Methylindoline- and 2-Methyl-1,2,3,4-tetrahydroquinoline-Derived Phosphoramidites and Their Applications in Iridium-Catalyzed Allylic Alkylation of Indoles.Synthesis(12),2076-2082.
MLA	刘文博,et al."Synthesis of 2-Methylindoline- and 2-Methyl-1,2,3,4-tetrahydroquinoline-Derived Phosphoramidites and Their Applications in Iridium-Catalyzed Allylic Alkylation of Indoles".Synthesis .12(2009):2076-2082.