Highly selective hydrohalogenation reaction of substituted 2,3-allenoates | |
Ma SM(麻生明) ; Wang GW(王光伟) | |
刊名 | Chin. J. Chem.
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1999 | |
卷号 | 17期号:5页码:545-549 |
ISSN号 | 1001-604X |
其他题名 | 2,3-联烯酸酯的高选择性氢卤化反应 |
通讯作者 | 麻生明 |
英文摘要 | The hydrohalogenation reaction of 1-alkyl substituted 1,2-allenyl carboxylic acid esters (1) with MX (M=Na, or Li, X=Cl, Br, I) afforded a mixture of β,γ-unsaturated 3-halo-3-alkenoates (2) and α,β-unsaturated 3-halo-2-alkenoates (3) in HOAc, while using a mixture of HOAc-CF=3CO=2H (1:1) or CF=3CO=2H as thereaction medium the corresponding reaction cleanly produced β, γ-unstaturated 3-halo-3-alkenoates (2) as the sole products in high yields. The subsequent coupling reactions were studied. |
学科主题 | 有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1002/cjoc.19990170517 |
语种 | 英语 |
WOS记录号 | WOS:000083814600016 |
公开日期 | 2013-01-15 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/11788] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Ma SM,Wang GW. Highly selective hydrohalogenation reaction of substituted 2,3-allenoates[J]. Chin. J. Chem.,1999,17(5):545-549. |
APA | 麻生明,&王光伟.(1999).Highly selective hydrohalogenation reaction of substituted 2,3-allenoates.Chin. J. Chem.,17(5),545-549. |
MLA | 麻生明,et al."Highly selective hydrohalogenation reaction of substituted 2,3-allenoates".Chin. J. Chem. 17.5(1999):545-549. |
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