Highly selective hydrohalogenation reaction of substituted 2,3-allenoates

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	Highly selective hydrohalogenation reaction of substituted 2,3-allenoates
	Ma SM(麻生明) ; Wang GW(王光伟)
刊名	Chin. J. Chem.
	1999
卷号	17 期号:5 页码:545-549
ISSN号	1001-604X
其他题名	2,3－联烯酸酯的高选择性氢卤化反应
通讯作者	麻生明
英文摘要	The hydrohalogenation reaction of 1-alkyl substituted 1,2-allenyl carboxylic acid esters (1) with MX (M=Na, or Li, X=Cl, Br, I) afforded a mixture of β，γ－unsaturated 3-halo-3-alkenoates (2) and α，β－unsaturated 3-halo-2-alkenoates (3) in HOAc, while using a mixture of HOAc-CF=3CO=2H (1:1) or CF=3CO=2H as thereaction medium the corresponding reaction cleanly produced β， γ－unstaturated 3-halo-3-alkenoates (2) as the sole products in high yields. The subsequent coupling reactions were studied.
学科主题	有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/cjoc.19990170517
语种	英语
WOS记录号	WOS:000083814600016
公开日期	2013-01-15
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/11788]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Ma SM,Wang GW. Highly selective hydrohalogenation reaction of substituted 2,3-allenoates[J]. Chin. J. Chem.,1999,17(5):545-549.
APA	麻生明,&王光伟.(1999).Highly selective hydrohalogenation reaction of substituted 2,3-allenoates.Chin. J. Chem.,17(5),545-549.
MLA	麻生明,et al."Highly selective hydrohalogenation reaction of substituted 2,3-allenoates".Chin. J. Chem. 17.5(1999):545-549.