Addition of diphenylphosphinodithioic acid and thioacetic acid with vinylidenecyclopropanes: reversed regioselectivities

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	Addition of diphenylphosphinodithioic acid and thioacetic acid with vinylidenecyclopropanes: reversed regioselectivities
	Li W(李炜) ; Shi M(施敏)
刊名	Tetrahedron
	2009
卷号	65 期号:34 页码:6815-6821
其他题名	二苯基膦酸以及硫代醋酸和亚甲基环丙烷的加成反应-相反的区域选择性
通讯作者	施敏
英文摘要	The reaction of vinylidenecyclopropanes 1 with diphenylphosphinodithioic acid produces the adducts 3 in good to high yields in toluene upon heating at 100 degrees C within 1 h, whereas adducts 5 are obtained in excellent yields in reversed regioselectivity from the reaction of 1 with thioacetic acid under identical conditions. The radical reaction processes have been discussed oil the basis of deuterium labeling experiment and the control experiments in the presence of radical inhibitors (TEMPO and BHT) or a proton scavenger (DTBMP). (C) 2009 Elsevier Ltd. All rights reserved.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.tet.2009.06.090
语种	英语
WOS记录号	WOS:000269282400004
公开日期	2013-01-09
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/10260]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Li W,Shi M. Addition of diphenylphosphinodithioic acid and thioacetic acid with vinylidenecyclopropanes: reversed regioselectivities[J]. Tetrahedron,2009,65(34):6815-6821.
APA	Li W,&Shi M.(2009).Addition of diphenylphosphinodithioic acid and thioacetic acid with vinylidenecyclopropanes: reversed regioselectivities.Tetrahedron,65(34),6815-6821.
MLA	Li W,et al."Addition of diphenylphosphinodithioic acid and thioacetic acid with vinylidenecyclopropanes: reversed regioselectivities".Tetrahedron 65.34(2009):6815-6821.