Gold(I)-Catalyzed cascade cyclization reaction: Highly regio- and diastereoselective intermolecular addition of water and alcohols to epoxy alkynes

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 金属有机化学国家重点实验室

	Gold(I)-Catalyzed cascade cyclization reaction: Highly regio- and diastereoselective intermolecular addition of water and alcohols to epoxy alkynes
	Dai LZ(戴伦治) ; Qi MJ(齐明娟) ; Shi YL(时永灵) ; Liu XG(刘旭光) ; Shi M(施敏)
刊名	Org. Lett.
	2007
卷号	9 期号:16 页码:3191-3194
其他题名	金催化的串联成环反应: 高区域和高非对映选择性的水和醇同环氧炔烃的加成反应
通讯作者	施敏
英文摘要	[GRAPHICS] We have developed a novel access to ketal skeletons through a highly regio- and diastereoselective intermolecular addition of water and alcohols to alkynyl epoxides catalyzed by gold(I). This procedure involves a domino three-membered ring-opening, 6-exo-cycloisomerization, and subsequent intra- or intermolecular nucleophilic addition to a double-bond sequence.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ol0713640
语种	英语
WOS记录号	WOS:000248315900059
公开日期	2013-01-09
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/10092]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Dai LZ,Qi MJ,Shi YL,et al. Gold(I)-Catalyzed cascade cyclization reaction: Highly regio- and diastereoselective intermolecular addition of water and alcohols to epoxy alkynes[J]. Org. Lett.,2007,9(16):3191-3194.
APA	Dai LZ,Qi MJ,Shi YL,Liu XG,&Shi M.(2007).Gold(I)-Catalyzed cascade cyclization reaction: Highly regio- and diastereoselective intermolecular addition of water and alcohols to epoxy alkynes.Org. Lett.,9(16),3191-3194.
MLA	Dai LZ,et al."Gold(I)-Catalyzed cascade cyclization reaction: Highly regio- and diastereoselective intermolecular addition of water and alcohols to epoxy alkynes".Org. Lett. 9.16(2007):3191-3194.