Synthesis of new NHC-rhodium and iridium complexes derived from 2,2 '-diaminobiphenyl and their catalytic activities toward hydrosilylation of ketones | |
Chen T(陈涛) ; Liu XG(刘旭光) ; Shi M(施敏) | |
刊名 | Tetrahedron
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2007 | |
卷号 | 63期号:23页码:4874-4880 |
ISSN号 | 0040-4020 |
其他题名 | 基于联苯胺的氮杂卡宾和金属铑和铱配合物的合成及其还原反应研究 |
英文摘要 | Four new N-heterocyclic carbene (NHC)-rhodium and iridium complexes derived from 2,2 '-diaminobiphenyl have been successfully synthesized and their structures have been unambiguously characterized by X-ray diffraction. Their catalytic activities for hydrosilylation of ketones with diphenylsilane were investigated. It was found that NHC-rhodium complex (6) is the best one among the four catalysts for the reduction of ketones. (c) 2007 Elsevier Ltd. All rights reserved. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1016/j.tet.2007.03.150 |
语种 | 英语 |
WOS记录号 | WOS:000248238600003 |
公开日期 | 2013-01-09 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/10090] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Chen T,Liu XG,Shi M. Synthesis of new NHC-rhodium and iridium complexes derived from 2,2 '-diaminobiphenyl and their catalytic activities toward hydrosilylation of ketones[J]. Tetrahedron,2007,63(23):4874-4880. |
APA | 陈涛,刘旭光,&施敏.(2007).Synthesis of new NHC-rhodium and iridium complexes derived from 2,2 '-diaminobiphenyl and their catalytic activities toward hydrosilylation of ketones.Tetrahedron,63(23),4874-4880. |
MLA | 陈涛,et al."Synthesis of new NHC-rhodium and iridium complexes derived from 2,2 '-diaminobiphenyl and their catalytic activities toward hydrosilylation of ketones".Tetrahedron 63.23(2007):4874-4880. |
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