Synthesis of new NHC-rhodium and iridium complexes derived from 2,2 '-diaminobiphenyl and their catalytic activities toward hydrosilylation of ketones

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	Synthesis of new NHC-rhodium and iridium complexes derived from 2,2 '-diaminobiphenyl and their catalytic activities toward hydrosilylation of ketones
	Chen T(陈涛) ; Liu XG(刘旭光) ; Shi M(施敏)
刊名	Tetrahedron
	2007
卷号	63 期号:23 页码:4874-4880
ISSN号	0040-4020
其他题名	基于联苯胺的氮杂卡宾和金属铑和铱配合物的合成及其还原反应研究
英文摘要	Four new N-heterocyclic carbene (NHC)-rhodium and iridium complexes derived from 2,2 '-diaminobiphenyl have been successfully synthesized and their structures have been unambiguously characterized by X-ray diffraction. Their catalytic activities for hydrosilylation of ketones with diphenylsilane were investigated. It was found that NHC-rhodium complex (6) is the best one among the four catalysts for the reduction of ketones. (c) 2007 Elsevier Ltd. All rights reserved.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.tet.2007.03.150
语种	英语
WOS记录号	WOS:000248238600003
公开日期	2013-01-09
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/10090]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Chen T,Liu XG,Shi M. Synthesis of new NHC-rhodium and iridium complexes derived from 2,2 '-diaminobiphenyl and their catalytic activities toward hydrosilylation of ketones[J]. Tetrahedron,2007,63(23):4874-4880.
APA	陈涛,刘旭光,&施敏.(2007).Synthesis of new NHC-rhodium and iridium complexes derived from 2,2 '-diaminobiphenyl and their catalytic activities toward hydrosilylation of ketones.Tetrahedron,63(23),4874-4880.
MLA	陈涛,et al."Synthesis of new NHC-rhodium and iridium complexes derived from 2,2 '-diaminobiphenyl and their catalytic activities toward hydrosilylation of ketones".Tetrahedron 63.23(2007):4874-4880.