聚茜素红-多壁碳纳米管复合膜修饰电极的研制及叶酸含量测定; Determination of Folic Acid by Composite Film Electrode Modified with Poly-Alizarin Red and Multi-walled Carbon Nanotubes | |
杜学萍 ; 娄童芳 ; 董莹 ; 屈建莹 ; DU Xue-ping ; LOU Tong-fang ; DONG Ying ; QU Jian-ying | |
刊名 | http://electrochem.xmu.edu.cn/CN/abstract/abstract10108.shtml
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2014-10-28 | |
关键词 | 叶酸 多壁碳纳米管 茜素红 poly-alizarin red multi-walled carbon nanotubes folic acid |
英文摘要 | 采用电聚合方法将茜素红(AR)非共价修饰到多壁碳纳米管(MWCNTs)上,制得了PAR/MWCNTs/GC电极,该电极对叶酸(FA)具有良好的电催化作用. 结果表明,在最佳实验条件下,在-0.63 V处叶酸还原峰电流与浓度(1.25×10-6 ~ 4.00×10-5 mol·L-1)呈现良好线性关系,相关系数0.9985. 用标准加入法检测了回收率,其值达92.0% ~ 102.0%. 该电极制作简单,有良好的稳定性.; The novel modified electrode was fabricated by electropolymerizing alizarin red onto the surface of multi-walled carbon nanotubes on glassy carbon electrode surface, which exhibited good electrocatalytic activity for folic acid. The experimental results showed that the reduction peak current of folic acid at -0.63 V was linear to its concentration over the range of 1.25×10-6 ~ 4.00×10-5 mol·L-1 in the optimized experimental conditions (R = 0.9985). Test for recovery was carried out by standard addition method, and the recovery ratios were in the range of 92.0% ~ 102.0%. The modified electrode was prepared simply with excellent stability, which provides a new feasible method for determination of folic acid.; 河南省教育厅科学技术研究重点计划项目(No.13A150077)资助; 作者联系地址:河南大学化学化工学院环境与分析科学研究所,河南 开封 475004; Author's Address: Institute of Environmental and Analytical Sciences, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China; 通讯作者E-mail:lilyqujy@126.com |
语种 | 中文 |
出版者 | 厦门大学《电化学》编辑部 |
内容类型 | 期刊论文 |
源URL | [http://dx.doi.org/10.13208/j.electrochem.131105] ![]() |
专题 | 2014年第20卷 |
推荐引用方式 GB/T 7714 | 杜学萍,娄童芳,董莹,等. 聚茜素红-多壁碳纳米管复合膜修饰电极的研制及叶酸含量测定, Determination of Folic Acid by Composite Film Electrode Modified with Poly-Alizarin Red and Multi-walled Carbon Nanotubes[J]. http://electrochem.xmu.edu.cn/CN/abstract/abstract10108.shtml,2014. |
APA | 杜学萍.,娄童芳.,董莹.,屈建莹.,DU Xue-ping.,...&QU Jian-ying.(2014).聚茜素红-多壁碳纳米管复合膜修饰电极的研制及叶酸含量测定.http://electrochem.xmu.edu.cn/CN/abstract/abstract10108.shtml. |
MLA | 杜学萍,et al."聚茜素红-多壁碳纳米管复合膜修饰电极的研制及叶酸含量测定".http://electrochem.xmu.edu.cn/CN/abstract/abstract10108.shtml (2014). |
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