有机电化学合成简谈; Brief Introduction of Organic Electrochemistry | |
王欢 ; 陆嘉星 ; WANG Huan ; LU Jia-Xing | |
刊名 | http://electrochem.xmu.edu.cn/CN/abstract/abstract9832.shtml
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2011-11-28 | |
关键词 | 有机电化学 电化学合成 绿色化学 organic electrochemistry electrosynthesis green chemistry |
英文摘要 | 本文简要介绍了有机电化学合成的体系,研究方法和技术及主要特征。以C=C类物质为例介绍了有机电化学合成中的各类反应,并以己二腈的电合成为例介绍了相应的工业化应用。试图以CO2的电化学固定利用为例介绍了有机电化学合成的研究动向。; Organic electrochemistry is a very useful tool for organic synthesis, not only because of the selective introduction or removal of electrons from organic molecules, but also for its green process. In this paper, electroorganic synthesis has been introduced from the systems, research methods and technologies to the characterization. Most of organic compounds could be electrochemically oxidized or reduced. Here, taking C=C compounds as an example, several kinds of electrochemical organic synthesis reactions are discussed, such as electrochemical addition, electrocatalytic dimrization, electropolymerization, etc. Electroorganic synthesis has been industrialized since 1960s. In this paper, electrosynthesis of adiponitrile was used as an example to introduce the manufacturing technique and technological improvement. Electrochemical fixation of CO2 is also introduced. At last, future outlook is also described.; 国家自然科学基金(20973066,21173085)资助; 作者联系地址:上海市绿色化学与化工过程绿色化重点实验室,华东师范大学化学系,上海 200062; Author's Address: Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China; 通讯作者E-mail:jxlu@chem.ecnu.edu.cn |
语种 | 中文 |
出版者 | 厦门大学《电化学》编辑部 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/58457] ![]() |
专题 | 2011年第17卷 |
推荐引用方式 GB/T 7714 | 王欢,陆嘉星,WANG Huan,等. 有机电化学合成简谈, Brief Introduction of Organic Electrochemistry[J]. http://electrochem.xmu.edu.cn/CN/abstract/abstract9832.shtml,2011. |
APA | 王欢,陆嘉星,WANG Huan,&LU Jia-Xing.(2011).有机电化学合成简谈.http://electrochem.xmu.edu.cn/CN/abstract/abstract9832.shtml. |
MLA | 王欢,et al."有机电化学合成简谈".http://electrochem.xmu.edu.cn/CN/abstract/abstract9832.shtml (2011). |
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