锂离子电池负极CaSnO3制备及性能; Preparation and Characterization of CaSnO3 Anode Material for Lithium Ion Batteries | |
孙冉 ; 刘子庚 ; 蒋亚琪 ; SUN Ran ; LIU Zi-Geng ; JIANG Ya-Qi | |
刊名 | http://electrochem.xmu.edu.cn/CN/abstract/abstract9819.shtml
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2011-11-28 | |
关键词 | CaSnO3 煅烧 锂离子电池 CaSnO3 calcination Li-ion battery. |
英文摘要 | 应用水热法合成前驱物CaSn(OH)6,经高温煅烧而得CaSnO3. XRD、SEM、DSC-TGA表征其物相、表面形貌和相变过程,调节溶剂水和乙醇比例,可有效地控制前驱物的形态,从立方块到内凹立方块乃至枝状结构变化,高温煅烧前驱体可得到CaSnO3样品。CaSnO3电极比容量为334.4 mAh/g,呈现出优良的循环寿命。; In this study the precursor CaSn(OH)6 was prepared via a hydrothermal process, and its composition, surface feature and phase-transition were characterized by XRD, SEM and DSC-TGA. The shapes of CaSn(OH)6 crystals were effectively controlled by adjusting the volumn ratio of H2O and CH3CH2OH solvents. Perovskite CaSnO3 could be obtained by calcination of CaSn(OH)6 at 800 ℃. The reversible capacity of 334.4 mAh/g with good cycling stability could be achieved with the CaSnO3 electrode.; 国家自然科学基金 21073145; 福建省重点科技项目 2009HZ0002-1; 2009Y0045; 作者联系地址:厦门大学 化学化工学院化学系,福建 厦门,361005; Author's Address: College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China; 通讯作者E-mail:yqjiang@xmu.edu.cn |
语种 | 中文 |
出版者 | 厦门大学《电化学》编辑部 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/58445] ![]() |
专题 | 2011年第17卷 |
推荐引用方式 GB/T 7714 | 孙冉,刘子庚,蒋亚琪,等. 锂离子电池负极CaSnO3制备及性能, Preparation and Characterization of CaSnO3 Anode Material for Lithium Ion Batteries[J]. http://electrochem.xmu.edu.cn/CN/abstract/abstract9819.shtml,2011. |
APA | 孙冉,刘子庚,蒋亚琪,SUN Ran,LIU Zi-Geng,&JIANG Ya-Qi.(2011).锂离子电池负极CaSnO3制备及性能.http://electrochem.xmu.edu.cn/CN/abstract/abstract9819.shtml. |
MLA | 孙冉,et al."锂离子电池负极CaSnO3制备及性能".http://electrochem.xmu.edu.cn/CN/abstract/abstract9819.shtml (2011). |
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