茴香醛的直接电氧化合成研究

CORC > 厦门大学 > 2011年第17卷

	茴香醛的直接电氧化合成研究;  Study on Direct Electro-Oxidation of Anisaldehyde
	吴玲玲 ; 朱英红 ; 李姗姗 ; 曾红燕 ; 马淳安 ; Wu Lin-lin ; Zhu Ying-hong ; Li Shan-shan ; Zeng Hong-yan ; Ma Chun-an
刊名	http://electrochem.xmu.edu.cn/CN/abstract/abstract9783.shtml
	2011-05-28
关键词	茴香醚电氧化茴香醛 anisole electro-oxidation anisaldehyde
英文摘要	应用循环伏安和恒电位电解法研究了茴香醚在铂电极上直接电氧化行为.考查扫描速率、反应底物浓度、支持电解质和溶剂对该电氧化行为的影响. 结果表明，茴香醚在铂电极上的氧化过程是不可逆的. 在丙酮溶液中，其响应峰电流最高，反应受扩散控制. 经GC-MS检测，主要氧化产物为茴香醛，选择性为66.5%.; University of Technology, Hangzhou 310032, Zhejiang,China) Abstract: The oxidation of anisole on Pt electrode was investigated by cyclic voltammery and constant potential electrolysis. The influence of scan rates, substrate concentration, supporting electrolytes and solvent were considered . The results show that the electro-oxidation process of anisole was irreversible. In this research the sulfuric acid was the best supporting electrolytes and acetone was the best solvent, and the process was controlled by diffusion . The product of constant potential electrolysis was charactered by GC-MS .The results show that the main products was anisaldehyde, and the selectivity was up to 66.5% when using acetone as solvent. ; 浙江省重点科技创新团队(2009R50002); 作者联系地址：浙江工业大学化学工程与材料学院，绿色化学合成技术国家重点实验室培育基地，浙江杭州310032; Author's Address: College of Chemical Engineering and Materials Science of Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry, Zhejiang University of Technology, Hangzhou 310032, Zhejiang,China; 通讯作者E-mail：science@zjut.edu.cn
语种	中文
出版者	厦门大学《电化学》编辑部
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/58411]
专题	2011年第17卷
推荐引用方式 GB/T 7714	吴玲玲,朱英红,李姗姗,等. 茴香醛的直接电氧化合成研究,  Study on Direct Electro-Oxidation of Anisaldehyde[J]. http://electrochem.xmu.edu.cn/CN/abstract/abstract9783.shtml,2011.
APA	吴玲玲.,朱英红.,李姗姗.,曾红燕.,马淳安.,...&Ma Chun-an.(2011).茴香醛的直接电氧化合成研究.http://electrochem.xmu.edu.cn/CN/abstract/abstract9783.shtml.
MLA	吴玲玲,et al."茴香醛的直接电氧化合成研究".http://electrochem.xmu.edu.cn/CN/abstract/abstract9783.shtml (2011).