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Li_4Ti_5O_(12)纳米片的合成及储锂性能研究; Preparation and Electrochemical Behavior of Li_4Ti_5O_(12) Nanosheets as Anode Material for Lithium Ion Battery
王怡菲 ; 唐宇峰 ; 仇征 ; 杨立 ; WANG Yi-fei ; TANG Yu-feng ; QIU Zheng ; YANG Li
刊名http://electrochem.xmu.edu.cn/CN/abstract/abstract8450.shtml
2010-02-28
关键词Li4Ti5O12 纳米片 离子液体 电解液 锂离子电池 Li4Ti5O12 nanosheet ionic liquid electrolyte lithium ion battery
英文摘要以无定形的水合二氧化钛为前驱物,水热法合成了200~400nm大小的Li4Ti5O12纳米片作为锂离子电池负极材料.XRD(X射线衍射)、SEM(扫描电子显微镜)和TEM(透射电镜)分析表征样品的物相结构、表观形貌;循环伏安、充放电循环和电化学交流阻抗技术分别测定该纳米Li4Ti5O12在有机电解液和室温离子液体S114TFSI电解液中的电化学性能.结果表明,该材料具有较高的放电容量和良好的循环性能,有望成为锂二次电池新型负极材料.; Spinel lithium titanate(Li4Ti5O12) nanosheets with a size range of 200 ~400 nm were synthesized by hydrothermal process from the amorphous hydrous titanium oxide precursors.The as-prepared products were characterized by X-ray powder diffraction(XRD),scanning electron microscopy(SEM) and transmission electron microscopy(TEM).The electrochemical behaviors of Li4Ti5O12 electrode in conventional organic electrolyte and ionic liquid electrolyte were investigated by using cyclic voltammetry,galvanostatic charge-discharge and AC impedance techniques.The experimental results indicate that the as-prepared nanostructured Li4Ti5O12,evaluated as anode material,exhibited good reversibility and cycle performance.It is expected to be a potential anode material for commerical battery applications.; 作者联系地址:上海交通大学化学化工学院;; Author's Address: School of Chemistry and Chemical Technology,Shanghai Jiao Tong University,Shanghai 200240,China
语种中文
出版者厦门大学《电化学》编辑部
内容类型期刊论文
源URL[http://dspace.xmu.edu.cn/handle/2288/58364]  
专题2010年第16卷
推荐引用方式
GB/T 7714
王怡菲,唐宇峰,仇征,等. Li_4Ti_5O_(12)纳米片的合成及储锂性能研究, Preparation and Electrochemical Behavior of Li_4Ti_5O_(12) Nanosheets as Anode Material for Lithium Ion Battery[J]. http://electrochem.xmu.edu.cn/CN/abstract/abstract8450.shtml,2010.
APA 王怡菲.,唐宇峰.,仇征.,杨立.,WANG Yi-fei.,...&YANG Li.(2010).Li_4Ti_5O_(12)纳米片的合成及储锂性能研究.http://electrochem.xmu.edu.cn/CN/abstract/abstract8450.shtml.
MLA 王怡菲,et al."Li_4Ti_5O_(12)纳米片的合成及储锂性能研究".http://electrochem.xmu.edu.cn/CN/abstract/abstract8450.shtml (2010).
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