聚合漆酚-镍配合物的电化学合成与性质研究

CORC > 厦门大学 > 2002年第8卷

	聚合漆酚-镍配合物的电化学合成与性质研究; Electrochemical Synthesis and Characterization of the Nickel Electropolyurushiol Coordination Polymer
	高锋 ; 沈国才 ; 唐洁渊 ; 章文贡 ; GAO Feng ; SHEN Guo_cai ; TANG Jie_yuan ; ZHANG Wen_gong
刊名	http://electrochem.xmu.edu.cn/CN/abstract/abstract9215.shtml
	2002-02-28
关键词	漆酚电化学聚合镍配合物 Urushiol Electrochemical polymerization Nickel Coordination polymer
英文摘要	探讨了漆酚 (EPU)的电化学聚合及其聚合漆酚镍配合物 (EPU_Ni2 +)的制备 .采用X光电子能谱、红外光谱、动态机械热分析 (DMTA)、TG_DTA、原子发射光谱 (AES)等手段对配合物(EPU_Ni2 +进行表征 .AES结果表明 :镍含量达 7.5 % .由于存在着Ni2 +与EPU的配位作用 ,并引起进一步交联 ,从而提高了玻璃化转变温度和耐热性能; The nickel electropolyurushiol coordination polymer(EPU Ni 2+ ) was obtained by the reaction between nickel chloride isopropyl alcohol solution with electropolyurushiol (EPU).The electrochemical polymerization of urushiol and the preparation of nickel electropolyurushiol coordination polymer were investigated.The coordination polymer was characterized by XPS,FT_IR,DMTA and AES methods,and its composition and structure were determined.The content of Ni 2+ reached up to 7.5%. It was shown that there was certain coordination between Ni 2+ and electropolyurushiol in the coordination polymer,thus cross_links were formed.Therefore the glass transition temperature of the coordination polymer increased and heat resistance was enhanced considerably.; 作者联系地址：福建师范大学高分子研究所,福建师范大学高分子研究所,福建师范大学高分子研究所,福建师范大学高分子研究所福建福州,350007 ,福建福州,350007 ,福建福州,350007 ,福建福州,350007; Author's Address: Institute of Polymer Science,Fujian Teachers University,Fuzhou 350007,China
语种	中文
出版者	厦门大学《电化学》编辑部
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/57714]
专题	2002年第8卷
推荐引用方式 GB/T 7714	高锋,沈国才,唐洁渊,等. 聚合漆酚-镍配合物的电化学合成与性质研究, Electrochemical Synthesis and Characterization of the Nickel Electropolyurushiol Coordination Polymer[J]. http://electrochem.xmu.edu.cn/CN/abstract/abstract9215.shtml,2002.
APA	高锋.,沈国才.,唐洁渊.,章文贡.,GAO Feng.,...&ZHANG Wen_gong.(2002).聚合漆酚-镍配合物的电化学合成与性质研究.http://electrochem.xmu.edu.cn/CN/abstract/abstract9215.shtml.
MLA	高锋,et al."聚合漆酚-镍配合物的电化学合成与性质研究".http://electrochem.xmu.edu.cn/CN/abstract/abstract9215.shtml (2002).