一类西弗碱基光致异构化分子在不同基底上的表面增强拉曼光谱(英文); Comparison in Surface Enhanced Raman Scattering on Salicylideneamine between Silver and Gold Colloid and Silver Mirror Substrate | |
赵冰 ; 尾崎幸样 ; ZHAO Bing 1 ; Yukihiro Ozaki 2 | |
刊名 | http://electrochem.xmu.edu.cn/CN/abstract/abstract9263.shtml
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2001-05-28 | |
关键词 | 表面增强 拉曼光谱 金、银、基底 SERS Photochromic Silver substrate Gold substrate |
英文摘要 | 由水杨醛衍生得到的Schiff碱由于其具有起因于受激分子内质子转移的光致 (热致 )变色性质而受到了人们的重视 .本文利用表面增强拉曼光谱研究了该类化合物在金、银基底及银溶胶表面上的拉曼光谱 ,比较了不同基底对吸附分子结构的影响; In recent years, the study of photochromic and thermochromic materials has grown because of their possible applications in the optical processing of information, in addition to the scientific interest. Salicylidineaniles is one of the prospective choices owing to their photochromism caused by intramolecular hydrogen transfer [1~3] (Fig.1). It is generally agreed that, in the salicylideneamine system, photoexcitation is followed by a rapid barrierless proton transfer and subsequent rearrangement to form a colored photoproduct [4] . The photochemistry of the system in fluid solution is different from that of the solid, even in fluid solution, the photo? and thermo?chromic behavior is changed with the polarity of solvent [5,6] . Although the study on these Schiff bases has been continuing for several decades, there is no conclusion on the photochromic mechanism and the structure of the photoproduct by now.; 作者联系地址:吉林大学超分子结构与谱学教育部重点实验室!吉林长春130023,日本关西学院大学理学部!日本西宫市662-8501; Author's Address: 1. Key Lab. for Supramolecular Structure and Spectroscopy of Ministry of Education, Jilin Univ., Changchun, 130023,China.2. School of Science, Kwansei?Gakuin Univ., Nishinomiya 662?8501, Japan; Detaile |
语种 | 中文 |
出版者 | 厦门大学《电化学》编辑部 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/57607] ![]() |
专题 | 2001年第7卷 |
推荐引用方式 GB/T 7714 | 赵冰,尾崎幸样,ZHAO Bing 1,等. 一类西弗碱基光致异构化分子在不同基底上的表面增强拉曼光谱(英文), Comparison in Surface Enhanced Raman Scattering on Salicylideneamine between Silver and Gold Colloid and Silver Mirror Substrate[J]. http://electrochem.xmu.edu.cn/CN/abstract/abstract9263.shtml,2001. |
APA | 赵冰,尾崎幸样,ZHAO Bing 1,&Yukihiro Ozaki 2.(2001).一类西弗碱基光致异构化分子在不同基底上的表面增强拉曼光谱(英文).http://electrochem.xmu.edu.cn/CN/abstract/abstract9263.shtml. |
MLA | 赵冰,et al."一类西弗碱基光致异构化分子在不同基底上的表面增强拉曼光谱(英文)".http://electrochem.xmu.edu.cn/CN/abstract/abstract9263.shtml (2001). |
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