New ESR-Electrochemical Cell Designs for Coaxial Microwave Cavity

CORC > 厦门大学 > 1998年第4卷

	New ESR-Electrochemical Cell Designs for Coaxial Microwave Cavity; New ESRElectrochemical Cell Designs for Coaxial Microwave Cavity
	Zhuang L(庄林) ; Lu JT(陆君涛) ; Zhuang Lin ; Lu Juntao
刊名	http://electrochem.xmu.edu.cn/CN/abstract/abstract9503.shtml
	1998-05-28
关键词	ESR 同步电化学电化学池设计 ESR Simultaneous electrochemistry Cell Design1 Introduction
英文摘要	本文报道了一种适用于同轴微波腔的新型ＥＳＲ—电化学池的设计。工作电极的长度可调节，部分屏蔽微波辐射的功能由上下两个屏蔽套承担。除了传统的螺线管，工作电极还可由打孔的金属筒、金属网、甚至复合材料制成。对电极可根据需要置于共振腔的外面或里面。总之，新设计灵活实用，适合更多的研究场合。本文列举了一些应用实例。; New cell designs for simultaneous electrochemical(EC) and electron spin resonance (ESR) measurements are reported for coaxial microwave cavity. Adjustable shieldings are introduced so that the working electrode can be much shorter than the full height of the cavity. Besides the traditional helical electrode, the working electrode can be cylinders made from metal plates, metallic meshes or even composite materials. The counter electrode can be placed either inside or outside the cavity. These features make the new designs more flexible than that previously reported. With a nonperforated cylindrical electrode, this cell can be used to determine the standard potential and the number of electrons of electrode reactions involving radicals. Other possible applications are also briefed.; 作者联系地址：武汉大学化学系; Author's Address: Dept. of Chem., Wuhan Univ., Wuhan 430072
语种	中文
出版者	厦门大学《电化学》编辑部
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/57395]
专题	1998年第4卷
推荐引用方式 GB/T 7714	Zhuang L,Lu JT,Zhuang Lin,et al. New ESR-Electrochemical Cell Designs for Coaxial Microwave Cavity, New ESRElectrochemical Cell Designs for Coaxial Microwave Cavity[J]. http://electrochem.xmu.edu.cn/CN/abstract/abstract9503.shtml,1998.
APA	庄林,陆君涛,Zhuang Lin,&Lu Juntao.(1998).New ESR-Electrochemical Cell Designs for Coaxial Microwave Cavity.http://electrochem.xmu.edu.cn/CN/abstract/abstract9503.shtml.
MLA	庄林,et al."New ESR-Electrochemical Cell Designs for Coaxial Microwave Cavity".http://electrochem.xmu.edu.cn/CN/abstract/abstract9503.shtml (1998).