甲苯间接电氧化作用──铅电极上Mn（Ⅱ）的阳极氧化

CORC > 厦门大学 > 1995年第1卷

	甲苯间接电氧化作用──铅电极上Mn（Ⅱ）的阳极氧化; An Indirect Electrochemical Oxidation of Toluene──Anodic Oxidation of Mn(Ⅱ) on the Lead Electrode
	王仲华 ; 华庆民 ; 陈贵才 ; 王仲权 ; 邱育南 ; 严兴国 ; Wang Zhonghua ; Hua Qingmin ; Chen Guaeai
刊名	http://electrochem.xmu.edu.cn/CN/abstract/abstract9745.shtml
	1995-05-28
关键词	电化学氢化 Mn（Ⅱ）离子 Mn（Ⅲ）离子铅电极 Electrochemical oxidation Manganic ion Manganous ion Lead electrode
英文摘要	研究了硫酸介质中（２～８ｍｏｌ·Ｌ－１Ｍｎ（Ⅱ）电化学氧化为Ｍｎ（Ⅱ）的反应过程。铅电极表面阳极氧化生成的ＰｂＯ＿２与Ｍｎ（Ⅱ）进行化学反应生成Ｍｎ（Ⅱ），Ｍｎ（Ⅱ）并不直接与电极完成电荷交换。设计的流动式电解池一般情况都能达到＞９０％的电流效率。; The electrochemical oxidation of Mn (Ⅱ) to Mn(Ⅱ) in concentrated H_2SO_4(2￣8 mol . L-1) at lead electrede has been studied. It is found that the electrede surface is oxidized toPbO_2 in a direct electrochemical reaction, then PbO_2formed reacts with Mn (Ⅱ) in a chemicalreaction. Some effects involves current density , concentration of H_2SO_4 , temperature and conversionwere evaluated. The rule of electrogenerated Mn (Ⅲ) in flow electrolysis cell were determined atseveral conditions. The current efficiency at greater than 90% is obtained in general.; 作者联系地址：大庆石化总厂，厦门大学化学系，茂名石油化工公司; Author's Address: Daqing Petrochemical Complex, Daqing 163714Wang Zhongquan;Qiu Yunan;Yan XingguoDept. of Chem. , Xiamen Univ.,Xiamen 361005
语种	中文
出版者	厦门大学《电化学》编辑部
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/57171]
专题	1995年第1卷
推荐引用方式 GB/T 7714	王仲华,华庆民,陈贵才,等. 甲苯间接电氧化作用──铅电极上Mn（Ⅱ）的阳极氧化, An Indirect Electrochemical Oxidation of Toluene──Anodic Oxidation of Mn(Ⅱ) on the Lead Electrode[J]. http://electrochem.xmu.edu.cn/CN/abstract/abstract9745.shtml,1995.
APA	王仲华.,华庆民.,陈贵才.,王仲权.,邱育南.,...&Chen Guaeai.(1995).甲苯间接电氧化作用──铅电极上Mn（Ⅱ）的阳极氧化.http://electrochem.xmu.edu.cn/CN/abstract/abstract9745.shtml.
MLA	王仲华,et al."甲苯间接电氧化作用──铅电极上Mn（Ⅱ）的阳极氧化".http://electrochem.xmu.edu.cn/CN/abstract/abstract9745.shtml (1995).