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	Synthesis, characterization, and antitumour activity of isonicotinamido-4-bis(2-chloroethyl)aminobenzaldimine complexes of some transition metals
	Zhao H(赵鸿)
	2000
关键词	ACID HYDRAZIDE LIGANDS DIOXOURANIUM(VI) HYDRAZONES COBALT STATE
英文摘要	Isonicotinamido-4-bis(2-chloroethyl)aminobenzaldimine (IBAB) was synthesized through multistep reactions and characterized by spectral methods. The complexes M(IBAB)(2)(NO3)(2) (M = copper(II), nickel(II), cobalt(II), iron(III), zinc(II), and cadmium(II)) were isolated and characterized by elemental analysis, IR, UV VIS, and EPR spectra. The results show that IBAB binding to the metals is bidentate. In copper complex, IBAB is coordinated to the metal through carbonyl oxygen and azomethine nitrogen atoms. In the other complexes, which can form polymeric structure, IBAB is coordinated to the metal ions via amide nitrogen and pyridine nitrogen atom. The molar conductivity and spectral data suggest an octahedral geometry for the nickel(II), cobalt(II), and iron(III) complexes, a planar geometry for the copper(II) complex and a tetrahedral stereochemistry for the zinc(II) and cadmium(II) complexes. The data of antitumour activities indicate that the complexes have a definite cytotoxicity effect.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/69926]
专题	物理技术－已发表论文
推荐引用方式 GB/T 7714	Zhao H. Synthesis, characterization, and antitumour activity of isonicotinamido-4-bis(2-chloroethyl)aminobenzaldimine complexes of some transition metals[J],2000.
APA	赵鸿.(2000).Synthesis, characterization, and antitumour activity of isonicotinamido-4-bis(2-chloroethyl)aminobenzaldimine complexes of some transition metals..
MLA	赵鸿."Synthesis, characterization, and antitumour activity of isonicotinamido-4-bis(2-chloroethyl)aminobenzaldimine complexes of some transition metals".(2000).

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