Direct spectrophotometric determination of chromium by microwave-oven induced flow-injection analysis | |
Zhao H(赵鸿) | |
1998 | |
关键词 | microwave spectrophotometric flow-injection chromium(VI) dibromocarboxyarsenazo dibromo-o-carborylchlorophonazo |
英文摘要 | Two sensitive flow-injection methods have been developed for the determination of traces of Cr(VI), based on the very efficient microwave-accelerated reactions of Cr2O72- with dibromocarboxyarsenazo (DBM-AsA, in System 1) and dibromo-o-carborylchlorophonazo (DBOK-CPA, in System 2). The reactions are followed spectrophotometrically by measuring the decrease in the absorbance of DBM-AsA at 535 nm or DBOK-CPA at 556 nm. The sampling frequency for both systems is 40 h(-1). The calibration graphs are Linear in the range between 1.62 and 27.0 mu g ml(-1), and 0.40 and 10.80 mu g ml(-1) for Systems 1 and 2, respectively. The respective detection limits are 0.087 and 0.10 mu g ml(-1). The methods were applied to determining traces of chromium in a steel sample and electroplating solutions with satisfactory results. (C) 1998 Published by Elsevier Science B.V. All rights reserved. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/69921] ![]() |
专题 | 物理技术-已发表论文 |
推荐引用方式 GB/T 7714 | Zhao H. Direct spectrophotometric determination of chromium by microwave-oven induced flow-injection analysis[J],1998. |
APA | 赵鸿.(1998).Direct spectrophotometric determination of chromium by microwave-oven induced flow-injection analysis.. |
MLA | 赵鸿."Direct spectrophotometric determination of chromium by microwave-oven induced flow-injection analysis".(1998). |
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