Highly enantioselective resolution of terminal epoxides with cross-linked polymeric salen-Co(III) complexes

	Highly enantioselective resolution of terminal epoxides with cross-linked polymeric salen-Co(III) complexes
	Song, YM; Chen, HL; Hu, XQ; Bai, CM; Zheng, Z
刊名	tetrahedron letters
	2003-09-08
卷号	44 期号:37 页码:7081-7085
产权排序	1;1
英文摘要	crosslinked polymeric salen-co(iii) complexes derived from a novel dialdehyde and a trialdehyde were synthesized and employed in the hydrolytic kinetic resolution (hkr) of terminal epoxides. up to 99%, ee were obtained with only 0.16-0.02 mol%,, of catalyst (based on catalytic unit). (c) 2003 elsevier ltd. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	hydrolytic kinetic resolution ; chiral co(salen) complexes ; ring-opening reactions ; asymmetric catalysis ; racemic epoxides ; epoxidation ; olefins ; 1,2-diols
收录类别	SCI ; IC ; CCR
原文出处	true
语种	英语
WOS记录号	WOS:000185151400025
公开日期	2010-11-30
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/82827]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Song, YM,Chen, HL,Hu, XQ,et al. Highly enantioselective resolution of terminal epoxides with cross-linked polymeric salen-Co(III) complexes[J]. tetrahedron letters,2003,44(37):7081-7085.
APA	Song, YM,Chen, HL,Hu, XQ,Bai, CM,&Zheng, Z.(2003).Highly enantioselective resolution of terminal epoxides with cross-linked polymeric salen-Co(III) complexes.tetrahedron letters,44(37),7081-7085.
MLA	Song, YM,et al."Highly enantioselective resolution of terminal epoxides with cross-linked polymeric salen-Co(III) complexes".tetrahedron letters 44.37(2003):7081-7085.