| Synthesis, structure and third-order non-linear optical properties of W/S cluster Fe(DMF)(6) W-2(mu(2)-S)2(S)S(4) | |
| Zhang ZX(张中新) | |
| 2007 | |
| 关键词 | homometal cluster solid-state reaction third-order non-linear optical properties |
| 英文摘要 | The homometal cluster [Fe(DMF)(6)][W-2(mu(2)-S)(2)S-4] 1 (DMF = dimethylformamide) was successfully synthesized by low-temperature solid-state reactions. X-ray single-crystal diffraction studies reveal that compound 1 is dinuclear anion cluster. The compound was characterized by elemental analyses, IR spectra and UV-vis spectra. The third-order non-linear optical (NLO) properties of the cluster were also investigated and exhibited non-linear rare saturation absorption (alpha(2) < 0) and self-defocusing performance with modulus of the hyperpolarizabilities 9.547 x 10(-31) esu for 1. (c) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 内容类型 | 期刊论文 |
| 源URL | [http://dspace.xmu.edu.cn/handle/2288/66164]  |
| 专题 | 数学科学－已发表论文 |
| 推荐引用方式 GB/T 7714 | Zhang ZX. Synthesis, structure and third-order non-linear optical properties of W/S cluster Fe(DMF)(6) W-2(mu(2)-S)2(S)S(4)[J],2007. |
| APA | 张中新.(2007).Synthesis, structure and third-order non-linear optical properties of W/S cluster Fe(DMF)(6) W-2(mu(2)-S)2(S)S(4).. |
| MLA | 张中新."Synthesis, structure and third-order non-linear optical properties of W/S cluster Fe(DMF)(6) W-2(mu(2)-S)2(S)S(4)".(2007). |
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