Experimental and Theoretical Study on Palladium-Catalyzed C-P Bond Formation via Direct Coupling of Triarylbismuths with P(O)-H Compounds | |
Wang, Tao ; Sang, Shuai ; Liu, Liu ; Qiao, Hongwei ; Gao, Yuxing ; Zhao, Yufen ; Wang T(王涛) ; Zhao YF(赵玉芬) | |
刊名 | http://dx.doi.org/10.1021/jo402392t
![]() |
2014-01-17 | |
关键词 | MOLECULAR-ORBITAL METHODS GAUSSIAN-TYPE BASIS MULTICOUPLING ORGANOMETALLIC NUCLEOPHILES POTENTIAL BASIS-SETS PHOSPHINE OXIDES ORGANOBISMUTH COMPOUNDS POLARIZATION FUNCTIONS ORGANIC-SYNTHESIS MILD CONDITIONS H-PHOSPHONATES |
英文摘要 | Chinese National Natural Science Foundation [21202135]; NFFTBS [J1210014]; National Basic Research Program of China [2012CB821600, 2013CB910700]; China Scholarship Council; A novel and highly efficient Pd-catalyzed cross-coupling of triarylbismuths with a variety of P(O)-H compounds has been developed that proceeds smoothly without exclusion of moisture or air and provides a general and powerful tool for the preparation of various valuable arylphosphonates, arylphosphinates, and arylphosphine oxides, with high atom-economy, operational simplicity of the procedure, and good to high yield. The coupling reaction is the first example of transition-metal-catalyzed C-P bond construction using triarylbismuth compounds as substrates. DFT calculations reveal that C-P bond formation is the rate-determing step. |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/90843] ![]() |
专题 | 生命科学-已发表论文 |
推荐引用方式 GB/T 7714 | Wang, Tao,Sang, Shuai,Liu, Liu,et al. Experimental and Theoretical Study on Palladium-Catalyzed C-P Bond Formation via Direct Coupling of Triarylbismuths with P(O)-H Compounds[J]. http://dx.doi.org/10.1021/jo402392t,2014. |
APA | Wang, Tao.,Sang, Shuai.,Liu, Liu.,Qiao, Hongwei.,Gao, Yuxing.,...&赵玉芬.(2014).Experimental and Theoretical Study on Palladium-Catalyzed C-P Bond Formation via Direct Coupling of Triarylbismuths with P(O)-H Compounds.http://dx.doi.org/10.1021/jo402392t. |
MLA | Wang, Tao,et al."Experimental and Theoretical Study on Palladium-Catalyzed C-P Bond Formation via Direct Coupling of Triarylbismuths with P(O)-H Compounds".http://dx.doi.org/10.1021/jo402392t (2014). |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论