Experimental and Theoretical Study on Palladium-Catalyzed C-P Bond Formation via Direct Coupling of Triarylbismuths with P(O)-H Compounds

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	Experimental and Theoretical Study on Palladium-Catalyzed C-P Bond Formation via Direct Coupling of Triarylbismuths with P(O)-H Compounds
	Wang, Tao ; Sang, Shuai ; Liu, Liu ; Qiao, Hongwei ; Gao, Yuxing ; Zhao, Yufen ; Wang T(王涛) ; Zhao YF(赵玉芬)
刊名	http://dx.doi.org/10.1021/jo402392t
	2014-01-17
关键词	MOLECULAR-ORBITAL METHODS GAUSSIAN-TYPE BASIS MULTICOUPLING ORGANOMETALLIC NUCLEOPHILES POTENTIAL BASIS-SETS PHOSPHINE OXIDES ORGANOBISMUTH COMPOUNDS POLARIZATION FUNCTIONS ORGANIC-SYNTHESIS MILD CONDITIONS H-PHOSPHONATES
英文摘要	Chinese National Natural Science Foundation [21202135]; NFFTBS [J1210014]; National Basic Research Program of China [2012CB821600, 2013CB910700]; China Scholarship Council; A novel and highly efficient Pd-catalyzed cross-coupling of triarylbismuths with a variety of P(O)-H compounds has been developed that proceeds smoothly without exclusion of moisture or air and provides a general and powerful tool for the preparation of various valuable arylphosphonates, arylphosphinates, and arylphosphine oxides, with high atom-economy, operational simplicity of the procedure, and good to high yield. The coupling reaction is the first example of transition-metal-catalyzed C-P bond construction using triarylbismuth compounds as substrates. DFT calculations reveal that C-P bond formation is the rate-determing step.
语种	英语
出版者	AMER CHEMICAL SOC
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/90843]
专题	生命科学－已发表论文
推荐引用方式 GB/T 7714	Wang, Tao,Sang, Shuai,Liu, Liu,et al. Experimental and Theoretical Study on Palladium-Catalyzed C-P Bond Formation via Direct Coupling of Triarylbismuths with P(O)-H Compounds[J]. http://dx.doi.org/10.1021/jo402392t,2014.
APA	Wang, Tao.,Sang, Shuai.,Liu, Liu.,Qiao, Hongwei.,Gao, Yuxing.,...&赵玉芬.(2014).Experimental and Theoretical Study on Palladium-Catalyzed C-P Bond Formation via Direct Coupling of Triarylbismuths with P(O)-H Compounds.http://dx.doi.org/10.1021/jo402392t.
MLA	Wang, Tao,et al."Experimental and Theoretical Study on Palladium-Catalyzed C-P Bond Formation via Direct Coupling of Triarylbismuths with P(O)-H Compounds".http://dx.doi.org/10.1021/jo402392t (2014).