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	Modeling for the catalytic coupling reaction of carbon monoxide to diethyl oxalate in fixed-bed reactors: Reactor model and its applications
	Zhu, Ya-Ping ; Tu, Song ; Luo, Zheng-Hong ; Luo ZH(罗正鸿)
	2012-09
关键词	Multiphase reactors Mathematical modeling Kinetics Fixed-bed reactor Catalytic coupling reaction
英文摘要	A two-dimensional (2D) pseudo-homogeneous reactor model was developed to simulate the performance of fixed-bed reactors for catalytic coupling reaction of carbon monoxide to diethyl oxalate. Reactor modeling was performed using a comprehensive numerical model consisting of two-dimensional coupled material and energy balance equations. A power law kinetic model was applied for simulating the catalytic coupling reaction with considering one main-reaction and two side-reactions. The validity of the reactor model was tested against the measured data from different-scale demonstration processes and satisfactory agreements between the model prediction and measured results were obtained. Furthermore, detailed numerical simulations were performed to investigate the effect of major operation parameters on the reactor behavior of fixed bed for catalytic coupling reaction of carbon monoxide to diethyl oxalate, and the result shows that the coolant temperature is the most sensitive parameter. (C) 2011 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.; National Natural Science Foundation of China [21076171]; State-Key Laboratory of Chemical Engineering (Tsinghua University) [SKL-ChE-10A03]; Fujian Province Science and Technology Office of China [2009HZ0005-1]
语种	英语
出版者	INST CHEMICAL ENGINEERS
内容类型	期刊论文
源URL	[http://dx.doi.org/10.1016/j.cherd.2011.12.004]
专题	生命科学－已发表论文
推荐引用方式 GB/T 7714	Zhu, Ya-Ping,Tu, Song,Luo, Zheng-Hong,et al. Modeling for the catalytic coupling reaction of carbon monoxide to diethyl oxalate in fixed-bed reactors: Reactor model and its applications[J],2012.
APA	Zhu, Ya-Ping,Tu, Song,Luo, Zheng-Hong,&罗正鸿.(2012).Modeling for the catalytic coupling reaction of carbon monoxide to diethyl oxalate in fixed-bed reactors: Reactor model and its applications..
MLA	Zhu, Ya-Ping,et al."Modeling for the catalytic coupling reaction of carbon monoxide to diethyl oxalate in fixed-bed reactors: Reactor model and its applications".(2012).

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