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	甲基丙烯酸酯嵌段共聚物的合成与表征; SYNTHESIS AND CHARACTERIZATION of BLOCKCOPOLYMERIZATION of METHACRYLATE
	戴李宗 ; 邹友思 ; 郑洪涛 ; 林国良 ; 潘容华
	1998
关键词	阴离子聚合 甲基丙烯酸酯 嵌段共聚物 聚合物结构 anionic polymerization methacrylate block copolymer polymer structure
英文摘要	研究了MMA和C7~9MA的阴离子共聚合，得到了A-b型嵌段共聚物。讨论了嵌段顺序、温度、引发剂及PC7~9MA-活性链长对MMA嵌段共聚的影响，认为，当第一嵌段单体为C7~9MA，T＝-20℃，［I］＝5.0~5.4x10-2MOl/l，Mn（PC7~9MA-）＜1.6x104时，有利于PC7~9MA-b-PMMA嵌段共聚物的合成；采用gPC、Ir、nMr对所得嵌段共聚物进行了表征。; The anionic block copolymerization MMA and C7￣9Methacrylate(C7￣9MA) was studied using nBuLi as initiator.PC7￣9MAbPMMA copolymer was obtained.The inFluence of monomer sequence, temperature, initiator and active chain length of PC7￣9MA- were discussed on block copolymerization.When T=-20 ℃,=0.50￣0.54×10-2 mol/L, C7￣9MA as First monomer, PC7￣9MA- with  n￣ 1.6×104 was Favorable to the synthesis of PC7￣9MA bPMMA block copolymer.The molecular weight and molecular weight distribution of copolymer were measured by GPC.The structure of block copolymer was characterized by FTIR and 1HNMR.; 国家自然科学基金
语种	zh_CN
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/107513]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	戴李宗,邹友思,郑洪涛,等. 甲基丙烯酸酯嵌段共聚物的合成与表征, SYNTHESIS AND CHARACTERIZATION of BLOCKCOPOLYMERIZATION of METHACRYLATE[J],1998.
APA	戴李宗,邹友思,郑洪涛,林国良,&潘容华.(1998).甲基丙烯酸酯嵌段共聚物的合成与表征..
MLA	戴李宗,et al."甲基丙烯酸酯嵌段共聚物的合成与表征".(1998).

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