Fischer-tropsch catalysts for the production of hydrocarbon fuels with high selectivity

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	Fischer-tropsch catalysts for the production of hydrocarbon fuels with high selectivity
	Zhang, Qinghong ; Cheng, Kang ; Kang, Jincan ; Deng, Weiping ; Wang, Ye ; Zhang QH(张庆红) ; Kang JC(康金灿) ; Deng WP(邓卫平) ; Wang Y(王野)
刊名	http://dx.doi.org/10.1002/cssc.201300797
	2014
关键词	Carbides Carbon nanotubes Catalysis Coal deposits Diesel fuels Fischer-Tropsch synthesis Functional groups Gasoline Hydrocarbons Hydrocracking Hydrogenation Metal nanoparticles Metals Methane Natural gas deposits Transition m
英文摘要	Fischer-Tropsch synthesis is a key reaction in the utilization of non-petroleum carbon resources, such as methane (natural gas, shale gas, and biogas), coal, and biomass, for the sustainable production of clean liquid fuels from synthesis gas. Selectivity control is one of the biggest challenges in Fischer-Tropsch synthesis. This Minireview focuses on the development of new catalysts with controllable product selectivities. Recent attempts to increase the selectivity to C5+ hydrocarbons by preparing catalysts with well-defined active phases or with new supports or by optimizing the interaction between the promoter and the active phase are briefly highlighted. Advances in developing bifunctional catalysts capable of catalyzing both CO hydrogenation to heavier hydrocarbons and hydrocracking/isomerization of heavier hydrocarbons are critically reviewed. It is demonstrated that the control of the secondary hydrocracking reactions by using core-shell nanostructures or solid-acid materials, such as mesoporous zeolites and carbon nanotubes with acid functional groups, is an effective strategy to tune the product selectivity of Fischer-Tropsch synthesis. Very promising selectivities to gasoline- and diesel-range hydrocarbons have been attained over some bifunctional catalysts. Split personality: Bifunctional catalysts containing both active metal (metal carbide) nanoparticles for CO hydrogenation and acid sites for hydrocracking/isomerization are very promising for the selective production of gasoline or diesel fuel (see picture). The control of secondary reactions by using new solid-acid materials, such as mesoporous zeolites, leads to outstanding product selectivity. ? 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89757]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Zhang, Qinghong,Cheng, Kang,Kang, Jincan,et al. Fischer-tropsch catalysts for the production of hydrocarbon fuels with high selectivity[J]. http://dx.doi.org/10.1002/cssc.201300797,2014.
APA	Zhang, Qinghong.,Cheng, Kang.,Kang, Jincan.,Deng, Weiping.,Wang, Ye.,...&王野.(2014).Fischer-tropsch catalysts for the production of hydrocarbon fuels with high selectivity.http://dx.doi.org/10.1002/cssc.201300797.
MLA	Zhang, Qinghong,et al."Fischer-tropsch catalysts for the production of hydrocarbon fuels with high selectivity".http://dx.doi.org/10.1002/cssc.201300797 (2014).