Interconversion between ruthenacyclohexadiene and ruthenabenzene: A combined experimental and theoretical study

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	Interconversion between ruthenacyclohexadiene and ruthenabenzene: A combined experimental and theoretical study
	Zhang, Hong ; Lin, Ran ; Li, Jinhua ; Zhu, Jun ; Xia, Haiping ; Zhang H(张弘) ; Zhu J(朱军) ; Xia HP(夏海平)
刊名	http://dx.doi.org/10.1021/om500550a
	2014
英文摘要	Treatment of ruthenabenzene [(C9H6NO)Ru{CC(PPh3)CHC(PPh3)CH}(C9H6NO)(PPh3)]Cl2 (1) with NaBH4 produces the first ruthenacyclohexa-1,4-diene [(C9H6NO)Ru{CC(PPh3)CH2C(PPh3)CH}(C9H6NO)(PPh3)]Cl (2), which was fully characterized. Under an oxygen atmosphere, complex 2 can easily convert to complex 1. DFT calculations were carried out to rationalize the high regioselectivity in the reaction of the ruthenabenene 1 with NaBH4 and the interconversion between 1 and 2. ? 2014 American Chemical Society.
语种	英语
出版者	American Chemical Society
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89705]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Zhang, Hong,Lin, Ran,Li, Jinhua,et al. Interconversion between ruthenacyclohexadiene and ruthenabenzene: A combined experimental and theoretical study[J]. http://dx.doi.org/10.1021/om500550a,2014.
APA	Zhang, Hong.,Lin, Ran.,Li, Jinhua.,Zhu, Jun.,Xia, Haiping.,...&夏海平.(2014).Interconversion between ruthenacyclohexadiene and ruthenabenzene: A combined experimental and theoretical study.http://dx.doi.org/10.1021/om500550a.
MLA	Zhang, Hong,et al."Interconversion between ruthenacyclohexadiene and ruthenabenzene: A combined experimental and theoretical study".http://dx.doi.org/10.1021/om500550a (2014).