Synthesis of long-sought C66 with exohedral stabilization

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	Synthesis of long-sought C66 with exohedral stabilization
	Gao, Cong-Li ; Li, Xiang ; Tan, Yuan-Zhi ; Wu, Xin-Zhou ; Zhang, Qianyan ; Xie, Su-Yuan ; Huang, Rong-Bin ; Zhang QY(张前炎) ; Xie SY(谢素原) ; Huang RB(黄荣彬)
刊名	http://dx.doi.org/10.1002/anie.201402625
	2014
关键词	Fullerenes Liquid chromatography X ray diffraction
英文摘要	Previously reported fused-pentagon fullerenes stabilized by exohedral derivatization do not share the same cage with those stabilized by endohedral encapsulation. Herein we report the crystallographic identification of #4348C66Cl10, which has the same cage as that of previously reported Sc2@C66. According to the geometrical data of #4348C66Cl10, both strain relief (at the fused pentagons) and local aromaticity (on the remaining sp 2-hybrided carbon framework) contribute to the exohedral stabilization of this long-sought 66 carbon atom cage. Captured at last! Elusive #4348C66 was stabilized exohedrally to give a fullerene derivative identified as #4348C66Cl10 by X-ray single-crystal diffraction (see picture). The isolation of this chlorofullerene supports the existence of #4348C66 in the carbon arc. ? 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
语种	英语
出版者	Wiley-VCH Verlag
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89692]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Gao, Cong-Li,Li, Xiang,Tan, Yuan-Zhi,et al. Synthesis of long-sought C66 with exohedral stabilization[J]. http://dx.doi.org/10.1002/anie.201402625,2014.
APA	Gao, Cong-Li.,Li, Xiang.,Tan, Yuan-Zhi.,Wu, Xin-Zhou.,Zhang, Qianyan.,...&黄荣彬.(2014).Synthesis of long-sought C66 with exohedral stabilization.http://dx.doi.org/10.1002/anie.201402625.
MLA	Gao, Cong-Li,et al."Synthesis of long-sought C66 with exohedral stabilization".http://dx.doi.org/10.1002/anie.201402625 (2014).