Higher alcohol synthesis from syngas over KCoMoP catalysts

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	Higher alcohol synthesis from syngas over KCoMoP catalysts
	Xu, Rulong ; Li, Yunhua ; Cao, Zhikai ; Zheng, Jinbao ; Zhang, Nuowei ; Chen, Binghui ; Wang, Wenju ; Li YH(李云华) ; Cao ZK(曹志凯) ; Zheng JB(郑进保) ; Chen BH(陈秉辉)
刊名	http://dx.doi.org/10.1016/j.catcom.2014.03.015
	2014
关键词	Carbon dioxide Cobalt compounds Indium phosphide Potassium Sol-gel process Sol-gels Synthesis gas
英文摘要	Carbon modified KxCo0.75MoP (0 ≤x≤ 1.5) catalysts were prepared from a sol-gel method using citric acid as a complexant. The catalysts were evaluated with CO hydrogenation and characterized by XRD, XPS and CO2-TPD techniques. Results show that the addition of cobalt accelerates the dispersion of catalytic components in phosphide catalysts while the participation of potassium in phosphide catalysts enhances the interaction between MoP and CoMoP and facilitates the rearrangement of electron density in different Mo species. In K1Co0.75MoP, a large number of Mo4 + species resulted in high selectivity to C2 + higher alcohol. ? 2014 Published by Elsevier B.V.
语种	英语
出版者	ELSEVIER SCIENCE BV
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89661]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Xu, Rulong,Li, Yunhua,Cao, Zhikai,et al. Higher alcohol synthesis from syngas over KCoMoP catalysts[J]. http://dx.doi.org/10.1016/j.catcom.2014.03.015,2014.
APA	Xu, Rulong.,Li, Yunhua.,Cao, Zhikai.,Zheng, Jinbao.,Zhang, Nuowei.,...&陈秉辉.(2014).Higher alcohol synthesis from syngas over KCoMoP catalysts.http://dx.doi.org/10.1016/j.catcom.2014.03.015.
MLA	Xu, Rulong,et al."Higher alcohol synthesis from syngas over KCoMoP catalysts".http://dx.doi.org/10.1016/j.catcom.2014.03.015 (2014).