A functionalized Ge-3-compound with a dual character of the central germanium atom

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	A functionalized Ge-3-compound with a dual character of the central germanium atom
	Li, Yan ; Mondal, Kartik Chandra ; Luebben, Jens ; Zhu, Hongping ; Dittrich, Birger ; Purushothaman, Indu ; Parameswaran, Pattiyil ; Roesky, Herbert W. ; Li Y(李彦) ; Zhu HP(朱红平)
刊名	http://dx.doi.org/10.1039/c3cc49635j
	2014
关键词	DOUBLE-BOND MAIN-GROUP GE CHEMISTRY COMPOUND CARBENES ADDUCTS SN SI
英文摘要	Deutsche Forschungs gemeinschaft [RO 224/60-1]; China Scholarship Council (CSC); (cAAC) Ge(GeL)(2) (1) (cAAC = cyclic alkyl(amino) carbene; L = PhC-(tBuN)(2)), a functionalized Ge-3-compound was prepared. Quantum mechanical studies on 1 show a reciprocal relationship between the electronic state of the central tri-coordinated Ge atom and its reactivity towards protons, viz. tetravalent Ge(0) in terms of bonding and divalent Ge(0) in terms of reactivity. Thus the central Ge atom can be considered as having a hidden but highly reactive lone pair of electrons. However, the terminal Ge atoms can be considered as tri-coordinated divalent Ge(I) with an active lone pair of electrons.
语种	英语
出版者	ROYAL SOC CHEMISTRY
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89471]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Li, Yan,Mondal, Kartik Chandra,Luebben, Jens,et al. A functionalized Ge-3-compound with a dual character of the central germanium atom[J]. http://dx.doi.org/10.1039/c3cc49635j,2014.
APA	Li, Yan.,Mondal, Kartik Chandra.,Luebben, Jens.,Zhu, Hongping.,Dittrich, Birger.,...&朱红平.(2014).A functionalized Ge-3-compound with a dual character of the central germanium atom.http://dx.doi.org/10.1039/c3cc49635j.
MLA	Li, Yan,et al."A functionalized Ge-3-compound with a dual character of the central germanium atom".http://dx.doi.org/10.1039/c3cc49635j (2014).