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Improved lithium ion battery performance by mesoporous Co3O4 nanosheets grown on self-standing NiSix nanowires on nickel foam
Chen, Huixin ; Zhang, Qiaobao ; Wang, Jiexi ; Xu, Daguo ; Li, Xinhai ; Yang, Yong ; Zhang, Kaili ; Yang Y(杨勇)
刊名http://dx.doi.org/10.1039/c4ta00967c
2014
关键词ENHANCED ELECTROCHEMICAL PERFORMANCE ANODE MATERIALS ENERGY-STORAGE RATE CAPABILITY NANOROD ARRAYS ELECTRODE MATERIALS HIGH-CAPACITY NANOSTRUCTURES ARCHITECTURES FABRICATION
英文摘要National Basic Research Program of China (973 program) [2011CB935903]; National Natural Science Foundation of China [21233004, 21021002]; City University of Hong Kong Seed Grant [7003023]; Novel three-dimensional (3D) hierarchical NiSix/Co3O4 core-shell nanowire arrays composed of NiSix nanowire cores and branched Co3O4 nanosheet shells have been successfully synthesized by combining chemical vapor deposition and a simple but effective chemical bath deposition process followed by a calcination process. The resulting hierarchical NiSix/Co3O4 core-shell nanowire arrays directly serve as binder- and conductive-agent-free electrodes for lithium ion batteries, which demonstrate remarkably improved electrochemical performances with excellent capacity retention and high rate capability on cycling. They can maintain a stable reversible capacity of 1279 mA h g(-1) after 100 cycles at a current density of 400 mA g(-1) and a capacity higher than 340 mA h g(-1) even at a current density as high as 8 A g(-1). Such superior electrochemical performance of the electrodes made by directly growing electro-active highly porous Co3O4 on a nanostructured NiSix conductive current collector makes them very promising for applications in high-performance lithium ion batteries.
语种英语
出版者ROYAL SOC CHEMISTRY
内容类型期刊论文
源URL[http://dspace.xmu.edu.cn/handle/2288/89435]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Chen, Huixin,Zhang, Qiaobao,Wang, Jiexi,et al. Improved lithium ion battery performance by mesoporous Co3O4 nanosheets grown on self-standing NiSix nanowires on nickel foam[J]. http://dx.doi.org/10.1039/c4ta00967c,2014.
APA Chen, Huixin.,Zhang, Qiaobao.,Wang, Jiexi.,Xu, Daguo.,Li, Xinhai.,...&杨勇.(2014).Improved lithium ion battery performance by mesoporous Co3O4 nanosheets grown on self-standing NiSix nanowires on nickel foam.http://dx.doi.org/10.1039/c4ta00967c.
MLA Chen, Huixin,et al."Improved lithium ion battery performance by mesoporous Co3O4 nanosheets grown on self-standing NiSix nanowires on nickel foam".http://dx.doi.org/10.1039/c4ta00967c (2014).
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