Efficient and convenient preparation of gamma-nonalactone, with use of a Dean-Stark trap to remove methanol

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	Efficient and convenient preparation of gamma-nonalactone, with use of a Dean-Stark trap to remove methanol
	Tu, Song ; Shen, Youyu ; Dong, Wan ; Yang, Jing ; Zhang, Chen ; Ye, Liyi ; Tu S(吐松) ; Yang J(杨静) ; Ye LY(叶李艺)
刊名	http://dx.doi.org/10.1007/s11164-013-1066-7
	2014
关键词	ASYMMETRIC-SYNTHESIS LACTONES ACID
英文摘要	National Nature Science Foundation of China [21106119]; Fundamental Research Funds for the Central Universities, P.R. China [2011121019]; Science and Technology Planning Project of Xiamen City, P.R. China [3502Z20113001]; We describe the development of an efficient and convenient process for preparation of gamma-nonalactone. The synthesis was accomplished by free-radical addition of methyl acrylate and n-hexanol. A Dean-Stark trap filled with water and n-hexanol was used to remove the methanol generated during the process. Orthogonal experiments were performed to optimize the reaction conditions, and the desired product, gamma-nonalactone, was produced in better than 70 % yield.
语种	英语
出版者	SPRINGER
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89342]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Tu, Song,Shen, Youyu,Dong, Wan,et al. Efficient and convenient preparation of gamma-nonalactone, with use of a Dean-Stark trap to remove methanol[J]. http://dx.doi.org/10.1007/s11164-013-1066-7,2014.
APA	Tu, Song.,Shen, Youyu.,Dong, Wan.,Yang, Jing.,Zhang, Chen.,...&叶李艺.(2014).Efficient and convenient preparation of gamma-nonalactone, with use of a Dean-Stark trap to remove methanol.http://dx.doi.org/10.1007/s11164-013-1066-7.
MLA	Tu, Song,et al."Efficient and convenient preparation of gamma-nonalactone, with use of a Dean-Stark trap to remove methanol".http://dx.doi.org/10.1007/s11164-013-1066-7 (2014).