Access to Chiral Tertiary alpha-Hydroxy-beta-Ynyl Esters via One-Pot Addition and Kinetic Resolution

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	Access to Chiral Tertiary alpha-Hydroxy-beta-Ynyl Esters via One-Pot Addition and Kinetic Resolution
	Chen, Hong-Bin ; Lai, Wen-Han ; Zhao, Yan ; Qin, Dan-Dan ; Ruan, Yuan-Ping ; Zhou, Zhao-Hui ; Chen HB(陈洪斌) ; Ruan YP(阮源萍)
刊名	http://dx.doi.org/10.1055/s-0033-1340824
	2014
关键词	HIGHLY ENANTIOSELECTIVE ALKYNYLATION ASYMMETRIC ALKYNE ADDITION PROPARGYLIC ALCOHOLS CATALYTIC ALKYNYLATION HENRY REACTIONS KETO ESTERS ALDEHYDES ACID AUXILIARIES COMPLEX
英文摘要	Fundamental Research Funds for the Central Universities [2010121014]; NSF of Fujian Province [2013J10011]; NFFTBS [J1310024]; Chiral amino alcohol promoted one-pot addition of zinc alkynylides to alpha-keto esters and kinetic resolution of the resulting tertiary propargylic alcohols was developed. The reaction provided us an alternative approach to access optically active tertiary alpha-hydroxy-beta-ynyl esters with enantiomeric excesses up to 98%.
语种	英语
出版者	GEORG THIEME VERLAG KG
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89339]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Chen, Hong-Bin,Lai, Wen-Han,Zhao, Yan,et al. Access to Chiral Tertiary alpha-Hydroxy-beta-Ynyl Esters via One-Pot Addition and Kinetic Resolution[J]. http://dx.doi.org/10.1055/s-0033-1340824,2014.
APA	Chen, Hong-Bin.,Lai, Wen-Han.,Zhao, Yan.,Qin, Dan-Dan.,Ruan, Yuan-Ping.,...&阮源萍.(2014).Access to Chiral Tertiary alpha-Hydroxy-beta-Ynyl Esters via One-Pot Addition and Kinetic Resolution.http://dx.doi.org/10.1055/s-0033-1340824.
MLA	Chen, Hong-Bin,et al."Access to Chiral Tertiary alpha-Hydroxy-beta-Ynyl Esters via One-Pot Addition and Kinetic Resolution".http://dx.doi.org/10.1055/s-0033-1340824 (2014).