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Effect of different carboxylates on two Ag(I) coordination polymers with 2,5-dimethylpyrazine ligand
Wang, Zhan-Hui ; Wang, Dan-Feng ; Zhang, Ting ; Huang, Rong-Bin ; Zheng, Lan-Sun ; Huang RB(黄荣彬) ; Zheng LS(郑兰荪)
刊名http://dx.doi.org/10.1016/j.molstruc.2014.01.030
2014-05-05
关键词METAL-ORGANIC FRAMEWORK COMPLEXES PHOTOLUMINESCENCE PROPERTY CATIONS ANION
英文摘要National Natural Science Foundation of China [21071118]; Two new metal-organic framework namely, [Ag-3(dmpyz)(15)(btc)](n) (1), and [Ag-2(dmpyz)(pta)](n) (2), have been synthesized and structurally characterized. Compound 1 is a 3D structure incorporating mu(5) - (eta(1), eta(1)) : (eta(1), eta(1)) : (eta(1), eta(1)) btc and mu(2) - N-1, N-1, mu(2) - N-2, N-3 dmpyz ligands. In compound 2, the mu(5) - eta(1) : eta(2) : eta(3) : eta(1) pta and the dmpyz ligands link the [Ag4O2] units into a 2D structure. It is noteworthy that the Ag center dot center dot center dot Ag interactions were observed in the two coordination polymers. The results show that the structural diversity of the polymers is mainly attributed to the usage of diverse ancillary carboxylate ligands. The thermal stabilities and photoluminescence behaviors were addressed. (C) 2014 Elsevier B.V. All rights reserved.
语种英语
出版者ELSEVIER SCIENCE BV
内容类型期刊论文
源URL[http://dspace.xmu.edu.cn/handle/2288/89304]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Wang, Zhan-Hui,Wang, Dan-Feng,Zhang, Ting,et al. Effect of different carboxylates on two Ag(I) coordination polymers with 2,5-dimethylpyrazine ligand[J]. http://dx.doi.org/10.1016/j.molstruc.2014.01.030,2014.
APA Wang, Zhan-Hui.,Wang, Dan-Feng.,Zhang, Ting.,Huang, Rong-Bin.,Zheng, Lan-Sun.,...&郑兰荪.(2014).Effect of different carboxylates on two Ag(I) coordination polymers with 2,5-dimethylpyrazine ligand.http://dx.doi.org/10.1016/j.molstruc.2014.01.030.
MLA Wang, Zhan-Hui,et al."Effect of different carboxylates on two Ag(I) coordination polymers with 2,5-dimethylpyrazine ligand".http://dx.doi.org/10.1016/j.molstruc.2014.01.030 (2014).
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