Synthesis of 6-Phenanthridinephosphonates via a Radical Phosphonation and Cyclization Process Mediated by Manganese(III) Acetate

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	Synthesis of 6-Phenanthridinephosphonates via a Radical Phosphonation and Cyclization Process Mediated by Manganese(III) Acetate
	Gao, Yuzhen ; Wu, Ju ; Xu, Jian ; Wang, Xuerui ; Tang, Guo ; Zhao, Yufen ; Tang G(唐果) ; Zhao YF(赵玉芬)
刊名	http://dx.doi.org/10.1002/ajoc.201402027
	2014
关键词	PHOSPHORUS-CENTERED RADICALS CATALYZED P-ARYLATION C-P ARYL HALIDES OXIDATIVE CYCLIZATION ORGANIC-SYNTHESIS PHOSPHINE OXIDES ROOM-TEMPERATURE H-PHOSPHONATES BOND FORMATION
英文摘要	National Basic Research Program of China [2012CB821600]; Chinese National Natural Science Foundation [21375113, 21173178, 21232005]; Program for Changjiang Scholars and Innovative Research Team in University; 6-Phenanthridinephosphonates have interesting biological activities and potential pharmaceutical applications. However, methods for preparing these compounds are very limited. In this report, dialkyl 6-phenanthridinephosphonates were synthesized through Mn(OAc)(3)-mediated radical phosphonation of 2-isocyanobiaryls in good to excellent yields under relatively mild reaction conditions. As one of its notable features, the radical process allows the direct formation of a P-C bond and the construction of a phenanthridine ring in one reaction.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89280]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Gao, Yuzhen,Wu, Ju,Xu, Jian,et al. Synthesis of 6-Phenanthridinephosphonates via a Radical Phosphonation and Cyclization Process Mediated by Manganese(III) Acetate[J]. http://dx.doi.org/10.1002/ajoc.201402027,2014.
APA	Gao, Yuzhen.,Wu, Ju.,Xu, Jian.,Wang, Xuerui.,Tang, Guo.,...&赵玉芬.(2014).Synthesis of 6-Phenanthridinephosphonates via a Radical Phosphonation and Cyclization Process Mediated by Manganese(III) Acetate.http://dx.doi.org/10.1002/ajoc.201402027.
MLA	Gao, Yuzhen,et al."Synthesis of 6-Phenanthridinephosphonates via a Radical Phosphonation and Cyclization Process Mediated by Manganese(III) Acetate".http://dx.doi.org/10.1002/ajoc.201402027 (2014).